<b>Preparation and reactivity studies of maleimidophenyl glycidylether with amines</b>

The hybrid thermosetting maleimido epoxy compound 4-(N-maleimidophenyl) glycidylether (N-MPGE) was prepared by reacting N-(4-hydroxyphenyl) maleimide (HPM) with epichlorohydrin by using benzyltrimethylammonium chloride as a catalyst. The resulting compound possessed both the oxirane ring and maleimi...

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Main Authors:	B. Lakshmi, K.N. Shivananda, K.N. Mahendra
Format:	Article
Language:	English
Published:	Chemical Society of Ethiopia 2011-04-01
Series:	Bulletin of the Chemical Society of Ethiopia
Subjects:	Amine Epoxy resin Maleimide Curing Epichlorohydrin
Online Access:	http://ajol.info/index.php/bcse/article/view/63366

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spelling	doaj-7fdc2b59bcc046be9647b76021f64a792020-11-24T21:53:36ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2011-04-012517382<b>Preparation and reactivity studies of maleimidophenyl glycidylether with amines</b>B. LakshmiK.N. ShivanandaK.N. MahendraThe hybrid thermosetting maleimido epoxy compound 4-(N-maleimidophenyl) glycidylether (N-MPGE) was prepared by reacting N-(4-hydroxyphenyl) maleimide (HPM) with epichlorohydrin by using benzyltrimethylammonium chloride as a catalyst. The resulting compound possessed both the oxirane ring and maleimide group. The curing reaction of N-MPGE with amines as curing agents such as tetraethylenepentamine (TEPA), bishexamethylenetriamine (BHMT), 2-methyl pentamethylenediamine (2-MPMDA) and 2,2,4-trimethy diamines (2,2,4-TMDA) was studied. The cured samples exhibited good thermal stability and excellent chemical (acid/alkali/solvent) and water absorption resistance. Morphological studies by the SEM technique further confirmed the phase homogeneity network of the cured systems.http://ajol.info/index.php/bcse/article/view/63366AmineEpoxy resinMaleimideCuringEpichlorohydrin
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	B. Lakshmi K.N. Shivananda K.N. Mahendra
spellingShingle	B. Lakshmi K.N. Shivananda K.N. Mahendra <b>Preparation and reactivity studies of maleimidophenyl glycidylether with amines</b> Bulletin of the Chemical Society of Ethiopia Amine Epoxy resin Maleimide Curing Epichlorohydrin
author_facet	B. Lakshmi K.N. Shivananda K.N. Mahendra
author_sort	B. Lakshmi
title	<b>Preparation and reactivity studies of maleimidophenyl glycidylether with amines</b>
title_short	<b>Preparation and reactivity studies of maleimidophenyl glycidylether with amines</b>
title_full	<b>Preparation and reactivity studies of maleimidophenyl glycidylether with amines</b>
title_fullStr	<b>Preparation and reactivity studies of maleimidophenyl glycidylether with amines</b>
title_full_unstemmed	<b>Preparation and reactivity studies of maleimidophenyl glycidylether with amines</b>
title_sort	<b>preparation and reactivity studies of maleimidophenyl glycidylether with amines</b>
publisher	Chemical Society of Ethiopia
series	Bulletin of the Chemical Society of Ethiopia
issn	1011-3924 1726-801X
publishDate	2011-04-01
description	The hybrid thermosetting maleimido epoxy compound 4-(N-maleimidophenyl) glycidylether (N-MPGE) was prepared by reacting N-(4-hydroxyphenyl) maleimide (HPM) with epichlorohydrin by using benzyltrimethylammonium chloride as a catalyst. The resulting compound possessed both the oxirane ring and maleimide group. The curing reaction of N-MPGE with amines as curing agents such as tetraethylenepentamine (TEPA), bishexamethylenetriamine (BHMT), 2-methyl pentamethylenediamine (2-MPMDA) and 2,2,4-trimethy diamines (2,2,4-TMDA) was studied. The cured samples exhibited good thermal stability and excellent chemical (acid/alkali/solvent) and water absorption resistance. Morphological studies by the SEM technique further confirmed the phase homogeneity network of the cured systems.
topic	Amine Epoxy resin Maleimide Curing Epichlorohydrin
url	http://ajol.info/index.php/bcse/article/view/63366
work_keys_str_mv	AT blakshmi bpreparationandreactivitystudiesofmaleimidophenylglycidyletherwithaminesb AT knshivananda bpreparationandreactivitystudiesofmaleimidophenylglycidyletherwithaminesb AT knmahendra bpreparationandreactivitystudiesofmaleimidophenylglycidyletherwithaminesb
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<b>Preparation and reactivity studies of maleimidophenyl glycidylether with amines</b>

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