Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117
Operating temperature can be a limiting factor in reliable applications of Proton Exchange Membrane (PEM) fuel cells. Nanoindentation tests were performed on perfluorosulfonic acid (PFSA) membranes (Nafion® 117) in order to study the influence of the temperature condition on their mechanical propert...
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2016-09-01
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doaj-7ffb027833174f78982618928baf37c62020-11-24T20:41:19ZengMDPI AGPolymers2073-43602016-09-018934410.3390/polym8090344polym8090344Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117Re Xia0Hongjian Zhou1Runni Wu2Wen-Ping Wu3School of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, ChinaSchool of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, ChinaSchool of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, ChinaDepartment of Engineering mechanics, School of Civil Engineering, Wuhan University, Wuhan 430072, ChinaOperating temperature can be a limiting factor in reliable applications of Proton Exchange Membrane (PEM) fuel cells. Nanoindentation tests were performed on perfluorosulfonic acid (PFSA) membranes (Nafion® 117) in order to study the influence of the temperature condition on their mechanical properties. The hardness and reduced modulus of Nafion® 117 were measured within a certain temperature range, from 10 to 70 °C. The results indicate that both hardness and elastic modulus show non-monotonic transition with the increase of the test temperature, with reaching peak values of 0.143 and 0.833 GPa at 45 °C. It also found that the membranes have a shape memory effect and a temperature dependent shape recovery ratio.http://www.mdpi.com/2073-4360/8/9/344perfluorosulfonic acid (PFSA) membranesNafion® 117temperature effectsmechanical propertiesnanoindentation |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Re Xia Hongjian Zhou Runni Wu Wen-Ping Wu |
spellingShingle |
Re Xia Hongjian Zhou Runni Wu Wen-Ping Wu Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117 Polymers perfluorosulfonic acid (PFSA) membranes Nafion® 117 temperature effects mechanical properties nanoindentation |
author_facet |
Re Xia Hongjian Zhou Runni Wu Wen-Ping Wu |
author_sort |
Re Xia |
title |
Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117 |
title_short |
Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117 |
title_full |
Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117 |
title_fullStr |
Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117 |
title_full_unstemmed |
Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117 |
title_sort |
nanoindentation investigation of temperature effects on the mechanical properties of nafion® 117 |
publisher |
MDPI AG |
series |
Polymers |
issn |
2073-4360 |
publishDate |
2016-09-01 |
description |
Operating temperature can be a limiting factor in reliable applications of Proton Exchange Membrane (PEM) fuel cells. Nanoindentation tests were performed on perfluorosulfonic acid (PFSA) membranes (Nafion® 117) in order to study the influence of the temperature condition on their mechanical properties. The hardness and reduced modulus of Nafion® 117 were measured within a certain temperature range, from 10 to 70 °C. The results indicate that both hardness and elastic modulus show non-monotonic transition with the increase of the test temperature, with reaching peak values of 0.143 and 0.833 GPa at 45 °C. It also found that the membranes have a shape memory effect and a temperature dependent shape recovery ratio. |
topic |
perfluorosulfonic acid (PFSA) membranes Nafion® 117 temperature effects mechanical properties nanoindentation |
url |
http://www.mdpi.com/2073-4360/8/9/344 |
work_keys_str_mv |
AT rexia nanoindentationinvestigationoftemperatureeffectsonthemechanicalpropertiesofnafion117 AT hongjianzhou nanoindentationinvestigationoftemperatureeffectsonthemechanicalpropertiesofnafion117 AT runniwu nanoindentationinvestigationoftemperatureeffectsonthemechanicalpropertiesofnafion117 AT wenpingwu nanoindentationinvestigationoftemperatureeffectsonthemechanicalpropertiesofnafion117 |
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