Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117

Operating temperature can be a limiting factor in reliable applications of Proton Exchange Membrane (PEM) fuel cells. Nanoindentation tests were performed on perfluorosulfonic acid (PFSA) membranes (Nafion® 117) in order to study the influence of the temperature condition on their mechanical propert...

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Main Authors: Re Xia, Hongjian Zhou, Runni Wu, Wen-Ping Wu
Format: Article
Language:English
Published: MDPI AG 2016-09-01
Series:Polymers
Subjects:
Online Access:http://www.mdpi.com/2073-4360/8/9/344
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spelling doaj-7ffb027833174f78982618928baf37c62020-11-24T20:41:19ZengMDPI AGPolymers2073-43602016-09-018934410.3390/polym8090344polym8090344Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117Re Xia0Hongjian Zhou1Runni Wu2Wen-Ping Wu3School of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, ChinaSchool of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, ChinaSchool of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, ChinaDepartment of Engineering mechanics, School of Civil Engineering, Wuhan University, Wuhan 430072, ChinaOperating temperature can be a limiting factor in reliable applications of Proton Exchange Membrane (PEM) fuel cells. Nanoindentation tests were performed on perfluorosulfonic acid (PFSA) membranes (Nafion® 117) in order to study the influence of the temperature condition on their mechanical properties. The hardness and reduced modulus of Nafion® 117 were measured within a certain temperature range, from 10 to 70 °C. The results indicate that both hardness and elastic modulus show non-monotonic transition with the increase of the test temperature, with reaching peak values of 0.143 and 0.833 GPa at 45 °C. It also found that the membranes have a shape memory effect and a temperature dependent shape recovery ratio.http://www.mdpi.com/2073-4360/8/9/344perfluorosulfonic acid (PFSA) membranesNafion® 117temperature effectsmechanical propertiesnanoindentation
collection DOAJ
language English
format Article
sources DOAJ
author Re Xia
Hongjian Zhou
Runni Wu
Wen-Ping Wu
spellingShingle Re Xia
Hongjian Zhou
Runni Wu
Wen-Ping Wu
Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117
Polymers
perfluorosulfonic acid (PFSA) membranes
Nafion® 117
temperature effects
mechanical properties
nanoindentation
author_facet Re Xia
Hongjian Zhou
Runni Wu
Wen-Ping Wu
author_sort Re Xia
title Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117
title_short Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117
title_full Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117
title_fullStr Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117
title_full_unstemmed Nanoindentation Investigation of Temperature Effects on the Mechanical Properties of Nafion® 117
title_sort nanoindentation investigation of temperature effects on the mechanical properties of nafion® 117
publisher MDPI AG
series Polymers
issn 2073-4360
publishDate 2016-09-01
description Operating temperature can be a limiting factor in reliable applications of Proton Exchange Membrane (PEM) fuel cells. Nanoindentation tests were performed on perfluorosulfonic acid (PFSA) membranes (Nafion® 117) in order to study the influence of the temperature condition on their mechanical properties. The hardness and reduced modulus of Nafion® 117 were measured within a certain temperature range, from 10 to 70 °C. The results indicate that both hardness and elastic modulus show non-monotonic transition with the increase of the test temperature, with reaching peak values of 0.143 and 0.833 GPa at 45 °C. It also found that the membranes have a shape memory effect and a temperature dependent shape recovery ratio.
topic perfluorosulfonic acid (PFSA) membranes
Nafion® 117
temperature effects
mechanical properties
nanoindentation
url http://www.mdpi.com/2073-4360/8/9/344
work_keys_str_mv AT rexia nanoindentationinvestigationoftemperatureeffectsonthemechanicalpropertiesofnafion117
AT hongjianzhou nanoindentationinvestigationoftemperatureeffectsonthemechanicalpropertiesofnafion117
AT runniwu nanoindentationinvestigationoftemperatureeffectsonthemechanicalpropertiesofnafion117
AT wenpingwu nanoindentationinvestigationoftemperatureeffectsonthemechanicalpropertiesofnafion117
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