Spectral and magnetic properties of impurity Tm3+ ions in YF3

Stark structure of 3H6, 3H5, 3H4, 3F4, 3F3, 3F2 and 1G4 multiplets of impurity non-Kramers Tm3+ ions in the orthorhombic YF3 crystal has been determined from luminescence studies. High frequency electron paramagnetic resonance (EPR) spectra (~ 207 GHz) of Tm3+ ions have been measured at temperature...

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Main Authors: A.V. Savinkov, G.S. Shakurov, I.E. Mumdzhi, B.Z. Malkin., S.I. Nikitin, S.L. Korableva, M.S. Tagirov
Format: Article
Language:English
Published: Kazan Federal University 2017-12-01
Series:Magnetic Resonance in Solids
Subjects:
EPR
Online Access:http://mrsej.kpfu.ru/contents/2017/MRSej_17202.pdf
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spelling doaj-80359a0db979469d9c35da1286c60a542020-11-25T00:42:39ZengKazan Federal UniversityMagnetic Resonance in Solids2072-59812017-12-0119217202Spectral and magnetic properties of impurity Tm3+ ions in YF3A.V. SavinkovG.S. Shakurov0I.E. Mumdzhi1B.Z. Malkin.2S.I. Nikitin3S.L. Korableva4M.S. Tagirov5Kazan Physical-Technical Institute, Sibirskiy trakt 10/7, Kazan 420029, RussiaKazan Federal University, Kremlevskaya 18, Kazan 420008, RussiaKazan Federal University, Kremlevskaya 18, Kazan 420008, RussiaKazan Federal University, Kremlevskaya 18, Kazan 420008, RussiaKazan Federal University, Kremlevskaya 18, Kazan 420008, RussiaKazan Federal University, Kremlevskaya 18, Kazan 420008, Russia; Institute of Perspective Research, TAS, L. Bulachnaya 36a, Kazan 420111, RussiaStark structure of 3H6, 3H5, 3H4, 3F4, 3F3, 3F2 and 1G4 multiplets of impurity non-Kramers Tm3+ ions in the orthorhombic YF3 crystal has been determined from luminescence studies. High frequency electron paramagnetic resonance (EPR) spectra (~ 207 GHz) of Tm3+ ions have been measured at temperature 4.2 K in external magnetic field applied perpendicular to the b-axis of YF3:Tm3+ single crystal. The results of measurements are interpreted in the frameworks of the crystal field theory. The set of crystal field parameters related to the crystallographic system of coordinates of the YF3 lattice has been obtained and used to reproduce satisfactory the crystal field energies and the EPR spectra.http://mrsej.kpfu.ru/contents/2017/MRSej_17202.pdfcrystal field parametersexchange charge modelEPRtrifluorides
collection DOAJ
language English
format Article
sources DOAJ
author A.V. Savinkov
G.S. Shakurov
I.E. Mumdzhi
B.Z. Malkin.
S.I. Nikitin
S.L. Korableva
M.S. Tagirov
spellingShingle A.V. Savinkov
G.S. Shakurov
I.E. Mumdzhi
B.Z. Malkin.
S.I. Nikitin
S.L. Korableva
M.S. Tagirov
Spectral and magnetic properties of impurity Tm3+ ions in YF3
Magnetic Resonance in Solids
crystal field parameters
exchange charge model
EPR
trifluorides
author_facet A.V. Savinkov
G.S. Shakurov
I.E. Mumdzhi
B.Z. Malkin.
S.I. Nikitin
S.L. Korableva
M.S. Tagirov
author_sort A.V. Savinkov
title Spectral and magnetic properties of impurity Tm3+ ions in YF3
title_short Spectral and magnetic properties of impurity Tm3+ ions in YF3
title_full Spectral and magnetic properties of impurity Tm3+ ions in YF3
title_fullStr Spectral and magnetic properties of impurity Tm3+ ions in YF3
title_full_unstemmed Spectral and magnetic properties of impurity Tm3+ ions in YF3
title_sort spectral and magnetic properties of impurity tm3+ ions in yf3
publisher Kazan Federal University
series Magnetic Resonance in Solids
issn 2072-5981
publishDate 2017-12-01
description Stark structure of 3H6, 3H5, 3H4, 3F4, 3F3, 3F2 and 1G4 multiplets of impurity non-Kramers Tm3+ ions in the orthorhombic YF3 crystal has been determined from luminescence studies. High frequency electron paramagnetic resonance (EPR) spectra (~ 207 GHz) of Tm3+ ions have been measured at temperature 4.2 K in external magnetic field applied perpendicular to the b-axis of YF3:Tm3+ single crystal. The results of measurements are interpreted in the frameworks of the crystal field theory. The set of crystal field parameters related to the crystallographic system of coordinates of the YF3 lattice has been obtained and used to reproduce satisfactory the crystal field energies and the EPR spectra.
topic crystal field parameters
exchange charge model
EPR
trifluorides
url http://mrsej.kpfu.ru/contents/2017/MRSej_17202.pdf
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