Spectral and magnetic properties of impurity Tm3+ ions in YF3
Stark structure of 3H6, 3H5, 3H4, 3F4, 3F3, 3F2 and 1G4 multiplets of impurity non-Kramers Tm3+ ions in the orthorhombic YF3 crystal has been determined from luminescence studies. High frequency electron paramagnetic resonance (EPR) spectra (~ 207 GHz) of Tm3+ ions have been measured at temperature...
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doaj-80359a0db979469d9c35da1286c60a542020-11-25T00:42:39ZengKazan Federal UniversityMagnetic Resonance in Solids2072-59812017-12-0119217202Spectral and magnetic properties of impurity Tm3+ ions in YF3A.V. SavinkovG.S. Shakurov0I.E. Mumdzhi1B.Z. Malkin.2S.I. Nikitin3S.L. Korableva4M.S. Tagirov5Kazan Physical-Technical Institute, Sibirskiy trakt 10/7, Kazan 420029, RussiaKazan Federal University, Kremlevskaya 18, Kazan 420008, RussiaKazan Federal University, Kremlevskaya 18, Kazan 420008, RussiaKazan Federal University, Kremlevskaya 18, Kazan 420008, RussiaKazan Federal University, Kremlevskaya 18, Kazan 420008, RussiaKazan Federal University, Kremlevskaya 18, Kazan 420008, Russia; Institute of Perspective Research, TAS, L. Bulachnaya 36a, Kazan 420111, RussiaStark structure of 3H6, 3H5, 3H4, 3F4, 3F3, 3F2 and 1G4 multiplets of impurity non-Kramers Tm3+ ions in the orthorhombic YF3 crystal has been determined from luminescence studies. High frequency electron paramagnetic resonance (EPR) spectra (~ 207 GHz) of Tm3+ ions have been measured at temperature 4.2 K in external magnetic field applied perpendicular to the b-axis of YF3:Tm3+ single crystal. The results of measurements are interpreted in the frameworks of the crystal field theory. The set of crystal field parameters related to the crystallographic system of coordinates of the YF3 lattice has been obtained and used to reproduce satisfactory the crystal field energies and the EPR spectra.http://mrsej.kpfu.ru/contents/2017/MRSej_17202.pdfcrystal field parametersexchange charge modelEPRtrifluorides |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
A.V. Savinkov G.S. Shakurov I.E. Mumdzhi B.Z. Malkin. S.I. Nikitin S.L. Korableva M.S. Tagirov |
spellingShingle |
A.V. Savinkov G.S. Shakurov I.E. Mumdzhi B.Z. Malkin. S.I. Nikitin S.L. Korableva M.S. Tagirov Spectral and magnetic properties of impurity Tm3+ ions in YF3 Magnetic Resonance in Solids crystal field parameters exchange charge model EPR trifluorides |
author_facet |
A.V. Savinkov G.S. Shakurov I.E. Mumdzhi B.Z. Malkin. S.I. Nikitin S.L. Korableva M.S. Tagirov |
author_sort |
A.V. Savinkov |
title |
Spectral and magnetic properties of impurity Tm3+ ions in YF3 |
title_short |
Spectral and magnetic properties of impurity Tm3+ ions in YF3 |
title_full |
Spectral and magnetic properties of impurity Tm3+ ions in YF3 |
title_fullStr |
Spectral and magnetic properties of impurity Tm3+ ions in YF3 |
title_full_unstemmed |
Spectral and magnetic properties of impurity Tm3+ ions in YF3 |
title_sort |
spectral and magnetic properties of impurity tm3+ ions in yf3 |
publisher |
Kazan Federal University |
series |
Magnetic Resonance in Solids |
issn |
2072-5981 |
publishDate |
2017-12-01 |
description |
Stark structure of 3H6, 3H5, 3H4, 3F4, 3F3, 3F2 and 1G4 multiplets of impurity non-Kramers Tm3+ ions in the orthorhombic YF3 crystal has been determined from luminescence studies. High frequency electron paramagnetic resonance (EPR) spectra (~ 207 GHz) of Tm3+ ions have been measured at temperature 4.2 K in external magnetic field applied perpendicular to the b-axis of YF3:Tm3+ single crystal. The results of measurements are interpreted in the frameworks of the crystal field theory. The set of crystal field parameters related to the crystallographic system of coordinates of the YF3 lattice has been obtained and used to reproduce satisfactory the crystal field energies and the EPR spectra. |
topic |
crystal field parameters exchange charge model EPR trifluorides |
url |
http://mrsej.kpfu.ru/contents/2017/MRSej_17202.pdf |
work_keys_str_mv |
AT avsavinkov spectralandmagneticpropertiesofimpuritytm3ionsinyf3 AT gsshakurov spectralandmagneticpropertiesofimpuritytm3ionsinyf3 AT iemumdzhi spectralandmagneticpropertiesofimpuritytm3ionsinyf3 AT bzmalkin spectralandmagneticpropertiesofimpuritytm3ionsinyf3 AT sinikitin spectralandmagneticpropertiesofimpuritytm3ionsinyf3 AT slkorableva spectralandmagneticpropertiesofimpuritytm3ionsinyf3 AT mstagirov spectralandmagneticpropertiesofimpuritytm3ionsinyf3 |
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