Recent Progress on Synthesis of <i>N</i>,<i>N</i>′-Chelate Organoboron Derivatives

<i>N</i>,<i>N</i>′-chelate organoboron compounds have been successfully applied in bioimaging, organic light-emitting diodes (OLEDs), functional polymer, photocatalyst, electroluminescent (EL) devices, and other science and technology areas. However, the concise and efficient...

Full description

Bibliographic Details
Main Authors: Tianbao Yang, Niu Tang, Qizhong Wan, Shuang-Feng Yin, Renhua Qiu
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/26/5/1401
Description
Summary:<i>N</i>,<i>N</i>′-chelate organoboron compounds have been successfully applied in bioimaging, organic light-emitting diodes (OLEDs), functional polymer, photocatalyst, electroluminescent (EL) devices, and other science and technology areas. However, the concise and efficient synthetic methods become more and more significant for material science, biomedical research, or other practical science. Here, we summarized the organoboron-<i>N</i>,<i>N</i>′-chelate derivatives and showed the different routes of their syntheses. Traditional methods to synthesize <i>N</i>,<i>N</i>′-chelate organoboron compounds were mainly using bidentate ligand containing nitrogen reacting with trivalent boron reagents. In this review, we described a series of bidentate ligands, such as bipyridine, 2-(pyridin-2-yl)-1<i>H</i>-indole, 2-(5-methyl-1<i>H</i>-pyrrol-2-yl)quinoline, <i>N</i>-(quinolin-8-yl)acetamide, 1,10-phenanthroline, and diketopyrrolopyrrole (DPP).
ISSN:1420-3049