Recent Progress on Synthesis of N,N′-Chelate Organoboron Derivatives

N,N′-chelate organoboron compounds have been successfully applied in bioimaging, organic light-emitting diodes (OLEDs), functional polymer, photocatalyst, electroluminescent (EL) devices, and other science and technology areas. However, the concise and efficient...

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Main Authors:	Tianbao Yang, Niu Tang, Qizhong Wan, Shuang-Feng Yin, Renhua Qiu
Format:	Article
Language:	English
Published:	MDPI AG 2021-03-01
Series:	Molecules
Subjects:	organoboron <i>N</i>,<i>N</i>′-chelate tetracoordinated fluorescent materials
Online Access:	https://www.mdpi.com/1420-3049/26/5/1401

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spelling	doaj-805afa1f6bd8401a9626529a57174f132021-03-06T00:02:59ZengMDPI AGMolecules1420-30492021-03-01261401140110.3390/molecules26051401Recent Progress on Synthesis of <i>N</i>,<i>N</i>′-Chelate Organoboron DerivativesTianbao Yang0Niu Tang1Qizhong Wan2Shuang-Feng Yin3Renhua Qiu4State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Institute of Shenzhen, Hunan University, Changsha 410082, ChinaState Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Institute of Shenzhen, Hunan University, Changsha 410082, ChinaState Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Institute of Shenzhen, Hunan University, Changsha 410082, ChinaState Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Institute of Shenzhen, Hunan University, Changsha 410082, ChinaState Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Institute of Shenzhen, Hunan University, Changsha 410082, China<i>N</i>,<i>N</i>′-chelate organoboron compounds have been successfully applied in bioimaging, organic light-emitting diodes (OLEDs), functional polymer, photocatalyst, electroluminescent (EL) devices, and other science and technology areas. However, the concise and efficient synthetic methods become more and more significant for material science, biomedical research, or other practical science. Here, we summarized the organoboron-<i>N</i>,<i>N</i>′-chelate derivatives and showed the different routes of their syntheses. Traditional methods to synthesize <i>N</i>,<i>N</i>′-chelate organoboron compounds were mainly using bidentate ligand containing nitrogen reacting with trivalent boron reagents. In this review, we described a series of bidentate ligands, such as bipyridine, 2-(pyridin-2-yl)-1<i>H</i>-indole, 2-(5-methyl-1<i>H</i>-pyrrol-2-yl)quinoline, <i>N</i>-(quinolin-8-yl)acetamide, 1,10-phenanthroline, and diketopyrrolopyrrole (DPP).https://www.mdpi.com/1420-3049/26/5/1401organoboron<i>N</i>,<i>N</i>′-chelatetetracoordinatedfluorescent materials
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Tianbao Yang Niu Tang Qizhong Wan Shuang-Feng Yin Renhua Qiu
spellingShingle	Tianbao Yang Niu Tang Qizhong Wan Shuang-Feng Yin Renhua Qiu Recent Progress on Synthesis of <i>N</i>,<i>N</i>′-Chelate Organoboron Derivatives Molecules organoboron <i>N</i>,<i>N</i>′-chelate tetracoordinated fluorescent materials
author_facet	Tianbao Yang Niu Tang Qizhong Wan Shuang-Feng Yin Renhua Qiu
author_sort	Tianbao Yang
title	Recent Progress on Synthesis of <i>N</i>,<i>N</i>′-Chelate Organoboron Derivatives
title_short	Recent Progress on Synthesis of <i>N</i>,<i>N</i>′-Chelate Organoboron Derivatives
title_full	Recent Progress on Synthesis of <i>N</i>,<i>N</i>′-Chelate Organoboron Derivatives
title_fullStr	Recent Progress on Synthesis of <i>N</i>,<i>N</i>′-Chelate Organoboron Derivatives
title_full_unstemmed	Recent Progress on Synthesis of <i>N</i>,<i>N</i>′-Chelate Organoboron Derivatives
title_sort	recent progress on synthesis of <i>n</i>,<i>n</i>′-chelate organoboron derivatives
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2021-03-01
description	<i>N</i>,<i>N</i>′-chelate organoboron compounds have been successfully applied in bioimaging, organic light-emitting diodes (OLEDs), functional polymer, photocatalyst, electroluminescent (EL) devices, and other science and technology areas. However, the concise and efficient synthetic methods become more and more significant for material science, biomedical research, or other practical science. Here, we summarized the organoboron-<i>N</i>,<i>N</i>′-chelate derivatives and showed the different routes of their syntheses. Traditional methods to synthesize <i>N</i>,<i>N</i>′-chelate organoboron compounds were mainly using bidentate ligand containing nitrogen reacting with trivalent boron reagents. In this review, we described a series of bidentate ligands, such as bipyridine, 2-(pyridin-2-yl)-1<i>H</i>-indole, 2-(5-methyl-1<i>H</i>-pyrrol-2-yl)quinoline, <i>N</i>-(quinolin-8-yl)acetamide, 1,10-phenanthroline, and diketopyrrolopyrrole (DPP).
topic	organoboron <i>N</i>,<i>N</i>′-chelate tetracoordinated fluorescent materials
url	https://www.mdpi.com/1420-3049/26/5/1401
work_keys_str_mv	AT tianbaoyang recentprogressonsynthesisofiniinichelateorganoboronderivatives AT niutang recentprogressonsynthesisofiniinichelateorganoboronderivatives AT qizhongwan recentprogressonsynthesisofiniinichelateorganoboronderivatives AT shuangfengyin recentprogressonsynthesisofiniinichelateorganoboronderivatives AT renhuaqiu recentprogressonsynthesisofiniinichelateorganoboronderivatives
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Recent Progress on Synthesis of <i>N</i>,<i>N</i>′-Chelate Organoboron Derivatives

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