SYNTHESIS OF NANO SIZED MESOPOROUS γ - Al2O3POWDER FROM DOMESTIC HAMEDAN KAOLIN

• Main Authors: Y. Kianinia, A. K. Darban, E. Taheri-Nassaj, B. Rahnama, A. Foroutan
• Format: Article
• Language: English
• Published: Iran University of Science & Technology 2015-03-01
• Series: Iranian Journal of Materials Science and Engineering
• Subjects: Nano- alumina; kaolin; Synthesis; precipitation
• Online Access: http://ijmse.iust.ac.ir/browse.php?a_code=A-10-127-77&slc_lang=en&sid=1

A method for producing high surface area nano-sized mesoporous alumina from inexpensive Iranian kaolin as raw material is proposed. In this method, first, kaolin was purified for purifying Kaolin, High Grade Magnetic Separation and leaching with HCl and chemical bleaching treatment by using sodium dithionite (Na 2 S 2O4 ) as reducing agent in acidic media (H 2SO 4 ) were used. Purified kaolin was calcined. After that, Al (hydr) oxide from acid -leachates of calcined kaolin was precipitated with ammonia, in presence of polyethylene glycol. Finally, a white powder of nano-sized alumina particles was obtained after calcination. BET surface area, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM) were used to characterize the sample. The resulting alumina with relatively high surface area (201.53 m 2 g -1 ) and narrow mean pore diameter (6.91 nm), consists of a particle size distribution ranging from 22 to 36 nm.