Dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2N,O]rhodium(I)

Dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2N,O]rhodium(I)

In the title compound, [Rh(C13H16NO)(CO)2], a square-planar coordination geometry is observed around the RhI atom, formed by the N and O atoms of the bidentate ligand and two C atoms from two carbonyl ligands. The RhI atom is displaced from the plane through these surrounding atoms by 0.0085&amp...

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Main Authors: Gertruida J. S. Venter, Gideon Steyl, Andreas Roodt
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812017175
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spelling doaj-81fce4597a8e4e8092f334c95b8722f92020-11-24T21:32:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m666m66710.1107/S1600536812017175Dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2N,O]rhodium(I)Gertruida J. S. VenterGideon SteylAndreas RoodtIn the title compound, [Rh(C13H16NO)(CO)2], a square-planar coordination geometry is observed around the RhI atom, formed by the N and O atoms of the bidentate ligand and two C atoms from two carbonyl ligands. The RhI atom is displaced from the plane through these surrounding atoms by 0.0085 (2) Å. The dihedral angle between the benzene ring and the N—C—C—C—O plane is 89.82 (6)°, and the N—Rh—O bite angle for the bidentate ligand is 90.53 (6)°. An intermolecular C—H...O interaction is observed between a methyl group of the benzene ring and a carbonyl O atom.http://scripts.iucr.org/cgi-bin/paper?S1600536812017175
collection DOAJ
language English
format Article
sources DOAJ
author Gertruida J. S. Venter
Gideon Steyl
Andreas Roodt
spellingShingle Gertruida J. S. Venter
Gideon Steyl
Andreas Roodt
Dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2N,O]rhodium(I)
Acta Crystallographica Section E
author_facet Gertruida J. S. Venter
Gideon Steyl
Andreas Roodt
author_sort Gertruida J. S. Venter
title Dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2N,O]rhodium(I)
title_short Dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2N,O]rhodium(I)
title_full Dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2N,O]rhodium(I)
title_fullStr Dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2N,O]rhodium(I)
title_full_unstemmed Dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2N,O]rhodium(I)
title_sort dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2n,o]rhodium(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-05-01
description In the title compound, [Rh(C13H16NO)(CO)2], a square-planar coordination geometry is observed around the RhI atom, formed by the N and O atoms of the bidentate ligand and two C atoms from two carbonyl ligands. The RhI atom is displaced from the plane through these surrounding atoms by 0.0085 (2) Å. The dihedral angle between the benzene ring and the N—C—C—C—O plane is 89.82 (6)°, and the N—Rh—O bite angle for the bidentate ligand is 90.53 (6)°. An intermolecular C—H...O interaction is observed between a methyl group of the benzene ring and a carbonyl O atom.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812017175
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AT andreasroodt dicarbonyl426dimethylphenylaminopent3en2onatoamp9542norhodiumi
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