Recent advances in the gold-catalyzed additions to C–C multiple bonds
C–O, C–N and C–C bonds are the most widespread types of bonds in nature, and are the cornerstone of most organic compounds, ranging from pharmaceuticals and agrochemicals to advanced materials and polymers. Cationic gold acts as a soft and carbophilic Lewis acid and is considered one of the most pow...
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doaj-82356a5e0b8b40e8a750cfc19daeb0fd2021-02-02T07:50:15ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972011-07-017189793610.3762/bjoc.7.1031860-5397-7-103Recent advances in the gold-catalyzed additions to C–C multiple bondsHe Huang0Yu Zhou1Hong Liu2State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, ChinaState Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, ChinaState Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, ChinaC–O, C–N and C–C bonds are the most widespread types of bonds in nature, and are the cornerstone of most organic compounds, ranging from pharmaceuticals and agrochemicals to advanced materials and polymers. Cationic gold acts as a soft and carbophilic Lewis acid and is considered one of the most powerful activators of C–C multiple bonds. Consequently, gold-catalysis plays an important role in the development of new strategies to form these bonds in more convenient ways. In this review, we highlight recent advances in the gold-catalyzed chemistry of addition of X–H (X = O, N, C) bonds to C–C multiple bonds, tandem reactions, and asymmetric additions. This review covers gold-catalyzed organic reactions published from 2008 to the present.https://doi.org/10.3762/bjoc.7.103asymmetric additioncatalysisgoldC−C multiple bondstandem reaction |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
He Huang Yu Zhou Hong Liu |
spellingShingle |
He Huang Yu Zhou Hong Liu Recent advances in the gold-catalyzed additions to C–C multiple bonds Beilstein Journal of Organic Chemistry asymmetric addition catalysis gold C−C multiple bonds tandem reaction |
author_facet |
He Huang Yu Zhou Hong Liu |
author_sort |
He Huang |
title |
Recent advances in the gold-catalyzed additions to C–C multiple bonds |
title_short |
Recent advances in the gold-catalyzed additions to C–C multiple bonds |
title_full |
Recent advances in the gold-catalyzed additions to C–C multiple bonds |
title_fullStr |
Recent advances in the gold-catalyzed additions to C–C multiple bonds |
title_full_unstemmed |
Recent advances in the gold-catalyzed additions to C–C multiple bonds |
title_sort |
recent advances in the gold-catalyzed additions to c–c multiple bonds |
publisher |
Beilstein-Institut |
series |
Beilstein Journal of Organic Chemistry |
issn |
1860-5397 |
publishDate |
2011-07-01 |
description |
C–O, C–N and C–C bonds are the most widespread types of bonds in nature, and are the cornerstone of most organic compounds, ranging from pharmaceuticals and agrochemicals to advanced materials and polymers. Cationic gold acts as a soft and carbophilic Lewis acid and is considered one of the most powerful activators of C–C multiple bonds. Consequently, gold-catalysis plays an important role in the development of new strategies to form these bonds in more convenient ways. In this review, we highlight recent advances in the gold-catalyzed chemistry of addition of X–H (X = O, N, C) bonds to C–C multiple bonds, tandem reactions, and asymmetric additions. This review covers gold-catalyzed organic reactions published from 2008 to the present. |
topic |
asymmetric addition catalysis gold C−C multiple bonds tandem reaction |
url |
https://doi.org/10.3762/bjoc.7.103 |
work_keys_str_mv |
AT hehuang recentadvancesinthegoldcatalyzedadditionstoccmultiplebonds AT yuzhou recentadvancesinthegoldcatalyzedadditionstoccmultiplebonds AT hongliu recentadvancesinthegoldcatalyzedadditionstoccmultiplebonds |
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1724298547546816512 |