Recent advances in the gold-catalyzed additions to C–C multiple bonds

C–O, C–N and C–C bonds are the most widespread types of bonds in nature, and are the cornerstone of most organic compounds, ranging from pharmaceuticals and agrochemicals to advanced materials and polymers. Cationic gold acts as a soft and carbophilic Lewis acid and is considered one of the most pow...

Full description

Bibliographic Details
Main Authors: He Huang, Yu Zhou, Hong Liu
Format: Article
Language:English
Published: Beilstein-Institut 2011-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.7.103
id doaj-82356a5e0b8b40e8a750cfc19daeb0fd
record_format Article
spelling doaj-82356a5e0b8b40e8a750cfc19daeb0fd2021-02-02T07:50:15ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972011-07-017189793610.3762/bjoc.7.1031860-5397-7-103Recent advances in the gold-catalyzed additions to C–C multiple bondsHe Huang0Yu Zhou1Hong Liu2State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, ChinaState Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, ChinaState Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, ChinaC–O, C–N and C–C bonds are the most widespread types of bonds in nature, and are the cornerstone of most organic compounds, ranging from pharmaceuticals and agrochemicals to advanced materials and polymers. Cationic gold acts as a soft and carbophilic Lewis acid and is considered one of the most powerful activators of C–C multiple bonds. Consequently, gold-catalysis plays an important role in the development of new strategies to form these bonds in more convenient ways. In this review, we highlight recent advances in the gold-catalyzed chemistry of addition of X–H (X = O, N, C) bonds to C–C multiple bonds, tandem reactions, and asymmetric additions. This review covers gold-catalyzed organic reactions published from 2008 to the present.https://doi.org/10.3762/bjoc.7.103asymmetric additioncatalysisgoldC−C multiple bondstandem reaction
collection DOAJ
language English
format Article
sources DOAJ
author He Huang
Yu Zhou
Hong Liu
spellingShingle He Huang
Yu Zhou
Hong Liu
Recent advances in the gold-catalyzed additions to C–C multiple bonds
Beilstein Journal of Organic Chemistry
asymmetric addition
catalysis
gold
C−C multiple bonds
tandem reaction
author_facet He Huang
Yu Zhou
Hong Liu
author_sort He Huang
title Recent advances in the gold-catalyzed additions to C–C multiple bonds
title_short Recent advances in the gold-catalyzed additions to C–C multiple bonds
title_full Recent advances in the gold-catalyzed additions to C–C multiple bonds
title_fullStr Recent advances in the gold-catalyzed additions to C–C multiple bonds
title_full_unstemmed Recent advances in the gold-catalyzed additions to C–C multiple bonds
title_sort recent advances in the gold-catalyzed additions to c–c multiple bonds
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2011-07-01
description C–O, C–N and C–C bonds are the most widespread types of bonds in nature, and are the cornerstone of most organic compounds, ranging from pharmaceuticals and agrochemicals to advanced materials and polymers. Cationic gold acts as a soft and carbophilic Lewis acid and is considered one of the most powerful activators of C–C multiple bonds. Consequently, gold-catalysis plays an important role in the development of new strategies to form these bonds in more convenient ways. In this review, we highlight recent advances in the gold-catalyzed chemistry of addition of X–H (X = O, N, C) bonds to C–C multiple bonds, tandem reactions, and asymmetric additions. This review covers gold-catalyzed organic reactions published from 2008 to the present.
topic asymmetric addition
catalysis
gold
C−C multiple bonds
tandem reaction
url https://doi.org/10.3762/bjoc.7.103
work_keys_str_mv AT hehuang recentadvancesinthegoldcatalyzedadditionstoccmultiplebonds
AT yuzhou recentadvancesinthegoldcatalyzedadditionstoccmultiplebonds
AT hongliu recentadvancesinthegoldcatalyzedadditionstoccmultiplebonds
_version_ 1724298547546816512