Local analysis of Eu2+ emission in CaAlSiN3

• Main Author: Benjamin Dierre, Takashi Takeda, Takashi Sekiguchi, Takayuki Suehiro, Kohsei Takahashi, Yoshinobu Yamamoto, Rong-Jun Xie and Naoto Hirosaki
• Format: Article
• Language: English
• Published: Taylor & Francis Group 2013-01-01
• Series: Science and Technology of Advanced Materials
• Online Access: http://dx.doi.org/10.1088/1468-6996/14/6/064201

We have investigated the local luminescence properties of Eu-doped CaAlSiN3 by using low-energy electron beam (e-beam) techniques. The particles yield broad emission centered at 655 nm with a shoulder at higher wavelength under light excitation, and a broad band around 643 nm with a tail at 540 nm under e-beam excitation. Using cathodoluminescence (CL) in a scanning electron microscope (SEM), we have observed small and large particles, which, although with different compositions, exhibit Eu2+-related emissions at 645 and 635 nm, respectively. Local CL measurements reveal that the Eu2+ emission may actually consist of several bands. In addition to the red broad band, regularly spaced sharp peaks have been occasionally observed. These luminescence variations may originate from a variation in the composition inside CaAlSiN3.