Bis[3-dimethylamino-1-(pyridin-2-yl)prop-2-en-1-one-κ2N1,O]tris(nitrato-κ2O,O)gadolinium(III) ethanol disolvate
In the title compound, [Gd(NO3)3(C10H12N2O)2]·2C2H5OH, the GdIII ion and one nitrate anion are located on a twofold rotation axis. The GdIII ion is ten-coordinated by two N and two O atoms from two bidentate 3-(N,N-dimethylamino)-1-(2-pyridyl)prop-2-en-1-one) ligands and six O atoms fro...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811050458 |
| Summary: | In the title compound, [Gd(NO3)3(C10H12N2O)2]·2C2H5OH, the GdIII ion and one nitrate anion are located on a twofold rotation axis. The GdIII ion is ten-coordinated by two N and two O atoms from two bidentate 3-(N,N-dimethylamino)-1-(2-pyridyl)prop-2-en-1-one) ligands and six O atoms from three nitrate anions in a distorted bicapped square-antiprismatic geometry. In the crystal, the components are linked by O—H...O hydrogen bonds. The ethanol solvent molecule is disordered over two positions in a ratio 0.615 (16):0.385 (16). |
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| ISSN: | 1600-5368 |