(2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2S,S′]cadmium(II) acetonitrile solvate

(2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2S,S′]cadmium(II) acetonitrile solvate

The title complex, [Cd(C6H12NOS2)2(C10H8N2)]·CH3CN, features a distorted octahedral N2S4 geometry for the CdII centre defined by a pair of asymmetrically chelating dithiocarbamate ligands as well as a 2,2′-bipyridine ligand. Supramolecular chains along [001] are formed in...

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Main Authors: Edward R. T. Tiekink, Juyoung C. Song
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809049666
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spelling doaj-85dbe99d10d3464389e16c674b03347b2020-11-25T01:35:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1669m167010.1107/S1600536809049666(2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2S,S′]cadmium(II) acetonitrile solvateEdward R. T. TiekinkJuyoung C. SongThe title complex, [Cd(C6H12NOS2)2(C10H8N2)]·CH3CN, features a distorted octahedral N2S4 geometry for the CdII centre defined by a pair of asymmetrically chelating dithiocarbamate ligands as well as a 2,2′-bipyridine ligand. Supramolecular chains along [001] are formed in the crystal structure, mediated by O—H...S hydrogen bonds; the acetonitrile solvent molecules are associated with the chains via O—H...N hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536809049666
collection DOAJ
language English
format Article
sources DOAJ
author Edward R. T. Tiekink
Juyoung C. Song
spellingShingle Edward R. T. Tiekink
Juyoung C. Song
(2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2S,S′]cadmium(II) acetonitrile solvate
Acta Crystallographica Section E
author_facet Edward R. T. Tiekink
Juyoung C. Song
author_sort Edward R. T. Tiekink
title (2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2S,S′]cadmium(II) acetonitrile solvate
title_short (2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2S,S′]cadmium(II) acetonitrile solvate
title_full (2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2S,S′]cadmium(II) acetonitrile solvate
title_fullStr (2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2S,S′]cadmium(II) acetonitrile solvate
title_full_unstemmed (2,2′-Bipyridyl)bis[N-(2-hydroxyethyl)-N-n-propyldithiocarbamato-κ2S,S′]cadmium(II) acetonitrile solvate
title_sort (2,2′-bipyridyl)bis[n-(2-hydroxyethyl)-n-n-propyldithiocarbamato-κ2s,s′]cadmium(ii) acetonitrile solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description The title complex, [Cd(C6H12NOS2)2(C10H8N2)]·CH3CN, features a distorted octahedral N2S4 geometry for the CdII centre defined by a pair of asymmetrically chelating dithiocarbamate ligands as well as a 2,2′-bipyridine ligand. Supramolecular chains along [001] are formed in the crystal structure, mediated by O—H...S hydrogen bonds; the acetonitrile solvent molecules are associated with the chains via O—H...N hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809049666
work_keys_str_mv AT edwardrttiekink 22amp8242bipyridylbisn2hydroxyethylnnpropyldithiocarbamatoamp9542ssamp8242cadmiumiiacetonitrilesolvate
AT juyoungcsong 22amp8242bipyridylbisn2hydroxyethylnnpropyldithiocarbamatoamp9542ssamp8242cadmiumiiacetonitrilesolvate
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