1,2,3-Triazolium macrocycles in supramolecular chemistry

1,2,3-Triazolium macrocycles in supramolecular chemistry

In this short review, we describe different pathways for synthesizing 1,2,3-triazolium macrocycles and focus on their application in different areas of supramolecular chemistry. The synthesis is mostly relying on the well-known “click reaction” (CuAAC) leading to 1,4-disubstituted 1,2,3-triazoles th...

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Bibliographic Details
Main Authors: Mastaneh Safarnejad Shad, Pulikkal Veettil Santhini, Wim Dehaen
Format: Article
Language:English
Published: Beilstein-Institut 2019-09-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
anion recognition
catenane
chalcogen bonding
click reaction
molecular reactor
hydrogen bonding
ph sensor
rotaxane
supramolecular
1,2,3-triazolium macrocycles
Online Access:https://doi.org/10.3762/bjoc.15.211
Description
Summary:In this short review, we describe different pathways for synthesizing 1,2,3-triazolium macrocycles and focus on their application in different areas of supramolecular chemistry. The synthesis is mostly relying on the well-known “click reaction” (CuAAC) leading to 1,4-disubstituted 1,2,3-triazoles that then can be quaternized. Applications of triazolium macrocycles thus prepared include receptors for molecular recognition of anionic species, pH sensors, mechanically interlocked molecules, molecular machines, and molecular reactors.
ISSN:1860-5397

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