1,2,3-Triazolium macrocycles in supramolecular chemistry
In this short review, we describe different pathways for synthesizing 1,2,3-triazolium macrocycles and focus on their application in different areas of supramolecular chemistry. The synthesis is mostly relying on the well-known “click reaction” (CuAAC) leading to 1,4-disubstituted 1,2,3-triazoles th...
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doaj-85f460a67e374a9299233f6f79c04f072021-02-02T03:46:36ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972019-09-011512142215510.3762/bjoc.15.2111860-5397-15-2111,2,3-Triazolium macrocycles in supramolecular chemistryMastaneh Safarnejad Shad0Pulikkal Veettil Santhini1Wim Dehaen2Molecular Design and Synthesis, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001 Leuven, BelgiumMolecular Design and Synthesis, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001 Leuven, BelgiumMolecular Design and Synthesis, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001 Leuven, BelgiumIn this short review, we describe different pathways for synthesizing 1,2,3-triazolium macrocycles and focus on their application in different areas of supramolecular chemistry. The synthesis is mostly relying on the well-known “click reaction” (CuAAC) leading to 1,4-disubstituted 1,2,3-triazoles that then can be quaternized. Applications of triazolium macrocycles thus prepared include receptors for molecular recognition of anionic species, pH sensors, mechanically interlocked molecules, molecular machines, and molecular reactors.https://doi.org/10.3762/bjoc.15.211anion recognitioncatenanechalcogen bondingclick reactionmolecular reactorhydrogen bondingph sensorrotaxanesupramolecular1,2,3-triazolium macrocycles |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Mastaneh Safarnejad Shad Pulikkal Veettil Santhini Wim Dehaen |
spellingShingle |
Mastaneh Safarnejad Shad Pulikkal Veettil Santhini Wim Dehaen 1,2,3-Triazolium macrocycles in supramolecular chemistry Beilstein Journal of Organic Chemistry anion recognition catenane chalcogen bonding click reaction molecular reactor hydrogen bonding ph sensor rotaxane supramolecular 1,2,3-triazolium macrocycles |
author_facet |
Mastaneh Safarnejad Shad Pulikkal Veettil Santhini Wim Dehaen |
author_sort |
Mastaneh Safarnejad Shad |
title |
1,2,3-Triazolium macrocycles in supramolecular chemistry |
title_short |
1,2,3-Triazolium macrocycles in supramolecular chemistry |
title_full |
1,2,3-Triazolium macrocycles in supramolecular chemistry |
title_fullStr |
1,2,3-Triazolium macrocycles in supramolecular chemistry |
title_full_unstemmed |
1,2,3-Triazolium macrocycles in supramolecular chemistry |
title_sort |
1,2,3-triazolium macrocycles in supramolecular chemistry |
publisher |
Beilstein-Institut |
series |
Beilstein Journal of Organic Chemistry |
issn |
1860-5397 |
publishDate |
2019-09-01 |
description |
In this short review, we describe different pathways for synthesizing 1,2,3-triazolium macrocycles and focus on their application in different areas of supramolecular chemistry. The synthesis is mostly relying on the well-known “click reaction” (CuAAC) leading to 1,4-disubstituted 1,2,3-triazoles that then can be quaternized. Applications of triazolium macrocycles thus prepared include receptors for molecular recognition of anionic species, pH sensors, mechanically interlocked molecules, molecular machines, and molecular reactors. |
topic |
anion recognition catenane chalcogen bonding click reaction molecular reactor hydrogen bonding ph sensor rotaxane supramolecular 1,2,3-triazolium macrocycles |
url |
https://doi.org/10.3762/bjoc.15.211 |
work_keys_str_mv |
AT mastanehsafarnejadshad 123triazoliummacrocyclesinsupramolecularchemistry AT pulikkalveettilsanthini 123triazoliummacrocyclesinsupramolecularchemistry AT wimdehaen 123triazoliummacrocyclesinsupramolecularchemistry |
_version_ |
1724307135960973312 |