The key role of Au-substrate interactions in catalytic gold subnanoclusters

The key role of Au-substrate interactions in catalytic gold subnanoclusters

Stabilization of gold nanoclusters in order to prevent their self-aggregation remains a great challenge. Here, the authors describe transient stabilization of very small catalytic gold subnanoclusters by alkyl chains or aromatic groups appended to the reactive π bond of simple alkynes.

Bibliographic Details
Main Authors: Jesús Cordón, Gonzalo Jiménez-Osés, José M. López-de-Luzuriaga, Miguel Monge
Format: Article
Language:English
Published: Nature Publishing Group 2017-11-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-017-01675-1
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spelling doaj-866f30c4e7514bd59d928a7a5565eac82021-05-11T07:25:41ZengNature Publishing GroupNature Communications2041-17232017-11-01811810.1038/s41467-017-01675-1The key role of Au-substrate interactions in catalytic gold subnanoclustersJesús Cordón0Gonzalo Jiménez-Osés1José M. López-de-Luzuriaga2Miguel Monge3Departamento de Química, Centro de Investigación en Síntesis Química, Universidad de La Rioja, Complejo Científico-TecnológicoDepartamento de Química, Centro de Investigación en Síntesis Química, Universidad de La Rioja, Complejo Científico-TecnológicoDepartamento de Química, Centro de Investigación en Síntesis Química, Universidad de La Rioja, Complejo Científico-TecnológicoDepartamento de Química, Centro de Investigación en Síntesis Química, Universidad de La Rioja, Complejo Científico-TecnológicoStabilization of gold nanoclusters in order to prevent their self-aggregation remains a great challenge. Here, the authors describe transient stabilization of very small catalytic gold subnanoclusters by alkyl chains or aromatic groups appended to the reactive π bond of simple alkynes.https://doi.org/10.1038/s41467-017-01675-1
collection DOAJ
language English
format Article
sources DOAJ
author Jesús Cordón
Gonzalo Jiménez-Osés
José M. López-de-Luzuriaga
Miguel Monge
spellingShingle Jesús Cordón
Gonzalo Jiménez-Osés
José M. López-de-Luzuriaga
Miguel Monge
The key role of Au-substrate interactions in catalytic gold subnanoclusters
Nature Communications
author_facet Jesús Cordón
Gonzalo Jiménez-Osés
José M. López-de-Luzuriaga
Miguel Monge
author_sort Jesús Cordón
title The key role of Au-substrate interactions in catalytic gold subnanoclusters
title_short The key role of Au-substrate interactions in catalytic gold subnanoclusters
title_full The key role of Au-substrate interactions in catalytic gold subnanoclusters
title_fullStr The key role of Au-substrate interactions in catalytic gold subnanoclusters
title_full_unstemmed The key role of Au-substrate interactions in catalytic gold subnanoclusters
title_sort key role of au-substrate interactions in catalytic gold subnanoclusters
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2017-11-01
description Stabilization of gold nanoclusters in order to prevent their self-aggregation remains a great challenge. Here, the authors describe transient stabilization of very small catalytic gold subnanoclusters by alkyl chains or aromatic groups appended to the reactive π bond of simple alkynes.
url https://doi.org/10.1038/s41467-017-01675-1
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