Crystal structures of dibromido{N-[(pyridin-2-yl-κN)methylidene]picolinohydrazide-κ2N′,O}cadmium methanol monosolvate and diiodido{N-[(pyridin-2-yl-κN)methylidene]picolinohydrazide-κ2N′,O}cadmium

Crystal structures of dibromido{N-[(pyridin-2-yl-κN)methylidene]picolinohydrazide-κ2N′,O}cadmium methanol monosolvate and diiodido{N-[(pyridin-2-yl-κN)methylidene]picolinohydrazide-κ2N′,O}cadmium

The title compounds, [CdBr2(C12H10N4O)]·CH3OH, (I), and [CdI2(C12H10N4O)], (II), are cadmium bromide and cadmium iodide complexes of the ligand (E)-N′-(pyridin-2-ylmethylene)picolinohydrazide. Complex (I) crystallizes as the methanol monosolvate. In both compounds, the Cd2+ cation is ligated by one...

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Bibliographic Details
Main Authors:	Ali Akbar Khandar, Farhad Akbari Afkhami, Harald Krautscheid, Kenneth Aase Kristoffersen, Zeliha Atioğlu, Mehmet Akkurt, Carl Henrik Görbitz
Format:	Article
Language:	English
Published:	International Union of Crystallography 2017-05-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure hydrazone: tridentate ligand cadmium bromide iodide hydrogen bonding
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989017005308

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