N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}benzohydrazide

N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}benzohydrazide

In the title compound, C27H27Cl2N7O4S, the amide groups bearing the N—S group and the tert-butyl group have s–trans conformations. The steric size of the tert-butyl and [(6-chloro-3-pyridyl)methyl]imidazolidin-2-ylidene groups cause the 2-chlorobenzoyl group and the benzy...

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Main Authors: Jian Shang, Qing-min Wang, Run-qiu Huang, Li Chen, Jianhua Gao
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809028943
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spelling doaj-879ae8b22dd74d3f941debdb2531be302020-11-25T01:34:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659o2131o213210.1107/S1600536809028943N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}benzohydrazideJian ShangQing-min WangRun-qiu HuangLi ChenJianhua GaoIn the title compound, C27H27Cl2N7O4S, the amide groups bearing the N—S group and the tert-butyl group have s–trans conformations. The steric size of the tert-butyl and [(6-chloro-3-pyridyl)methyl]imidazolidin-2-ylidene groups cause the 2-chlorobenzoyl group and the benzyol group to be directed away from one another, forming a dihedral angle of 60.62 (17)°. The central N—N bond adopts a gauche conformation with a C—N—N—C torsion angle of −79.1 (2)°. http://scripts.iucr.org/cgi-bin/paper?S1600536809028943
collection DOAJ
language English
format Article
sources DOAJ
author Jian Shang
Qing-min Wang
Run-qiu Huang
Li Chen
Jianhua Gao
spellingShingle Jian Shang
Qing-min Wang
Run-qiu Huang
Li Chen
Jianhua Gao
N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}benzohydrazide
Acta Crystallographica Section E
author_facet Jian Shang
Qing-min Wang
Run-qiu Huang
Li Chen
Jianhua Gao
author_sort Jian Shang
title N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}benzohydrazide
title_short N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}benzohydrazide
title_full N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}benzohydrazide
title_fullStr N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}benzohydrazide
title_full_unstemmed N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}benzohydrazide
title_sort n′-benzoyl-n-tert-butyl-2-chloro-n′-{[3-(6-chloro-3-pyridylmethyl)-2-nitriminoimidazolidin-1-yl]sulfanyl}benzohydrazide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description In the title compound, C27H27Cl2N7O4S, the amide groups bearing the N—S group and the tert-butyl group have s–trans conformations. The steric size of the tert-butyl and [(6-chloro-3-pyridyl)methyl]imidazolidin-2-ylidene groups cause the 2-chlorobenzoyl group and the benzyol group to be directed away from one another, forming a dihedral angle of 60.62 (17)°. The central N—N bond adopts a gauche conformation with a C—N—N—C torsion angle of −79.1 (2)°.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809028943
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AT qingminwang namp8242benzoylntertbutyl2chloronamp824236chloro3pyridylmethyl2nitriminoimidazolidin1ylsulfanylbenzohydrazide
AT runqiuhuang namp8242benzoylntertbutyl2chloronamp824236chloro3pyridylmethyl2nitriminoimidazolidin1ylsulfanylbenzohydrazide
AT lichen namp8242benzoylntertbutyl2chloronamp824236chloro3pyridylmethyl2nitriminoimidazolidin1ylsulfanylbenzohydrazide
AT jianhuagao namp8242benzoylntertbutyl2chloronamp824236chloro3pyridylmethyl2nitriminoimidazolidin1ylsulfanylbenzohydrazide
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