Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)mercury(II) acetonitrile hemisolvate
The asymmetric unit of the title compound, [HgCl2(C26H20N2)]·0.5CH3CN, contains two crystallographically independent [HgCl2(C26H20N2)] molecules and one acetonitrile solvent molecule. The HgII atoms are four-coordinated in distorted tetrahedral configurations by two N atoms from 2,9-dim...
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International Union of Crystallography
2009-08-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809024180 |
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doaj-881184800e3448f6bd9ed0b01010bb372020-11-25T02:19:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m848m84910.1107/S1600536809024180Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)mercury(II) acetonitrile hemisolvateVahid AmaniZeinab KhoshtarkibKhadijeh KalatehRobabeh AlizadehRoya AhmadiThe asymmetric unit of the title compound, [HgCl2(C26H20N2)]·0.5CH3CN, contains two crystallographically independent [HgCl2(C26H20N2)] molecules and one acetonitrile solvent molecule. The HgII atoms are four-coordinated in distorted tetrahedral configurations by two N atoms from 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligands and two Cl atoms. The ligand ring systems are not planar. The phenyl rings are oriented at dihedral angles of 74.61 (3) and 66.00 (3)° in the two molecules. In the crystal structure, π–π contacts between phenanthroline rings [centroid–centroid distances = 3.809 (1), 3.686 (1), 3.986 (1), 3.877 (1), 3.697 (1), 3.789 (1), 3.745 (1), 3.797 (1) and 3.638 (1) Å] may stabilize the structure. http://scripts.iucr.org/cgi-bin/paper?S1600536809024180 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Vahid Amani Zeinab Khoshtarkib Khadijeh Kalateh Robabeh Alizadeh Roya Ahmadi |
spellingShingle |
Vahid Amani Zeinab Khoshtarkib Khadijeh Kalateh Robabeh Alizadeh Roya Ahmadi Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)mercury(II) acetonitrile hemisolvate Acta Crystallographica Section E |
author_facet |
Vahid Amani Zeinab Khoshtarkib Khadijeh Kalateh Robabeh Alizadeh Roya Ahmadi |
author_sort |
Vahid Amani |
title |
Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)mercury(II) acetonitrile hemisolvate |
title_short |
Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)mercury(II) acetonitrile hemisolvate |
title_full |
Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)mercury(II) acetonitrile hemisolvate |
title_fullStr |
Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)mercury(II) acetonitrile hemisolvate |
title_full_unstemmed |
Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)mercury(II) acetonitrile hemisolvate |
title_sort |
dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2n,n′)mercury(ii) acetonitrile hemisolvate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2009-08-01 |
description |
The asymmetric unit of the title compound, [HgCl2(C26H20N2)]·0.5CH3CN, contains two crystallographically independent [HgCl2(C26H20N2)] molecules and one acetonitrile solvent molecule. The HgII atoms are four-coordinated in distorted tetrahedral configurations by two N atoms from 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligands and two Cl atoms. The ligand ring systems are not planar. The phenyl rings are oriented at dihedral angles of 74.61 (3) and 66.00 (3)° in the two molecules. In the crystal structure, π–π contacts between phenanthroline rings [centroid–centroid distances = 3.809 (1), 3.686 (1), 3.986 (1), 3.877 (1), 3.697 (1), 3.789 (1), 3.745 (1), 3.797 (1) and 3.638 (1) Å] may stabilize the structure. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809024180 |
work_keys_str_mv |
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