(Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate

(Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate

In the hydrated title complex, [Mn(C8H6N3O2)(CH3CO2)(C12H8N2)(H2O)2]·2H2O, the MnII atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted...

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Main Author: Ling Zeng
Format: Article
Language:English
Published: International Union of Crystallography 2012-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812007404
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spelling doaj-8815f4ebda004985a56aae2fa22e1ed62020-11-24T21:55:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m329m32910.1107/S1600536812007404(Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) dihydrateLing ZengIn the hydrated title complex, [Mn(C8H6N3O2)(CH3CO2)(C12H8N2)(H2O)2]·2H2O, the MnII atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted cis-MnN2O4 octahedral coordination geometry. The water O atoms are in a trans arrangement and one of them forms an intramolecular O—H...O hydrogen bond to the uncoordinated O atom of the acetate ion. In the crystal, the complex molecules and water molecules are connected by O—H...O and O—H...N hydrogen bonds to generate a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536812007404
collection DOAJ
language English
format Article
sources DOAJ
author Ling Zeng
spellingShingle Ling Zeng
(Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate
Acta Crystallographica Section E
author_facet Ling Zeng
author_sort Ling Zeng
title (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate
title_short (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate
title_full (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate
title_fullStr (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate
title_full_unstemmed (Acetato-κO)diaqua[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate
title_sort (acetato-κo)diaqua[2-(1h-benzotriazol-1-yl)acetato-κo](1,10-phenanthroline-κ2n,n′)manganese(ii) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-03-01
description In the hydrated title complex, [Mn(C8H6N3O2)(CH3CO2)(C12H8N2)(H2O)2]·2H2O, the MnII atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted cis-MnN2O4 octahedral coordination geometry. The water O atoms are in a trans arrangement and one of them forms an intramolecular O—H...O hydrogen bond to the uncoordinated O atom of the acetate ion. In the crystal, the complex molecules and water molecules are connected by O—H...O and O—H...N hydrogen bonds to generate a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812007404
work_keys_str_mv AT lingzeng acetatoamp954odiaqua21hbenzotriazol1ylacetatoamp954o110phenanthrolineamp9542nnamp8242manganeseiidihydrate
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