9-(3-Bromo-5-chloro-2-hydroxyphenyl)-10-(2-hydroxyethyl)-3,6-diphenyl-3,4,9,10-tetrahydroacridine-1,8(2H,5H)-dione

In the title compound, C33H27BrClNO4, the dihydropyridine ring adopts a flattened boat conformation. The molecular conformation is stabilized by an intramolecular O—H...O hydrogen bond, with an S(8) ring motif. In the crystal, O—H...O, C—H...O and C—H...Cl hydrogen bonds, and C—H...π interactions li...

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Main Authors: Mehmet Akkurt, Shaaban K. Mohamed, Antar A. Abdelhamid, Abdel-Aal M. Gaber, Mustafa R. Albayati
Format: Article
Language:English
Published: International Union of Crystallography 2014-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814010460
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spelling doaj-88177d54ff8f43fca5620bbd9d0fd9db2020-11-25T02:34:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-06-01706o663o66410.1107/S1600536814010460hg53959-(3-Bromo-5-chloro-2-hydroxyphenyl)-10-(2-hydroxyethyl)-3,6-diphenyl-3,4,9,10-tetrahydroacridine-1,8(2H,5H)-dioneMehmet Akkurt0Shaaban K. Mohamed1Antar A. Abdelhamid2Abdel-Aal M. Gaber3Mustafa R. Albayati4Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, TurkeyChemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, EnglandChemistry Department, Faculty of Science, Sohag University, 82524 Sohag, EgyptDepartment of Chemistry, Faculty of Science, Assiut University, 71516 Assiut, EgyptKirkuk University, College of Science, Department of Chemistry, Kirkuk, IraqIn the title compound, C33H27BrClNO4, the dihydropyridine ring adopts a flattened boat conformation. The molecular conformation is stabilized by an intramolecular O—H...O hydrogen bond, with an S(8) ring motif. In the crystal, O—H...O, C—H...O and C—H...Cl hydrogen bonds, and C—H...π interactions link the molecules, forming a three-dimensional network. In the acridinedione ring system, the two ring C atoms at the 2- and 3-positions, and the C atom at the 6-position and the atoms of the phenyl ring attached to the C atom at the 6-position are disordered over two sets of sites with occupancy ratios of 0.783 (5):0.217 (5) and 0.526 (18):0.474 (18), respectively.http://scripts.iucr.org/cgi-bin/paper?S1600536814010460
collection DOAJ
language English
format Article
sources DOAJ
author Mehmet Akkurt
Shaaban K. Mohamed
Antar A. Abdelhamid
Abdel-Aal M. Gaber
Mustafa R. Albayati
spellingShingle Mehmet Akkurt
Shaaban K. Mohamed
Antar A. Abdelhamid
Abdel-Aal M. Gaber
Mustafa R. Albayati
9-(3-Bromo-5-chloro-2-hydroxyphenyl)-10-(2-hydroxyethyl)-3,6-diphenyl-3,4,9,10-tetrahydroacridine-1,8(2H,5H)-dione
Acta Crystallographica Section E
author_facet Mehmet Akkurt
Shaaban K. Mohamed
Antar A. Abdelhamid
Abdel-Aal M. Gaber
Mustafa R. Albayati
author_sort Mehmet Akkurt
title 9-(3-Bromo-5-chloro-2-hydroxyphenyl)-10-(2-hydroxyethyl)-3,6-diphenyl-3,4,9,10-tetrahydroacridine-1,8(2H,5H)-dione
title_short 9-(3-Bromo-5-chloro-2-hydroxyphenyl)-10-(2-hydroxyethyl)-3,6-diphenyl-3,4,9,10-tetrahydroacridine-1,8(2H,5H)-dione
title_full 9-(3-Bromo-5-chloro-2-hydroxyphenyl)-10-(2-hydroxyethyl)-3,6-diphenyl-3,4,9,10-tetrahydroacridine-1,8(2H,5H)-dione
title_fullStr 9-(3-Bromo-5-chloro-2-hydroxyphenyl)-10-(2-hydroxyethyl)-3,6-diphenyl-3,4,9,10-tetrahydroacridine-1,8(2H,5H)-dione
title_full_unstemmed 9-(3-Bromo-5-chloro-2-hydroxyphenyl)-10-(2-hydroxyethyl)-3,6-diphenyl-3,4,9,10-tetrahydroacridine-1,8(2H,5H)-dione
title_sort 9-(3-bromo-5-chloro-2-hydroxyphenyl)-10-(2-hydroxyethyl)-3,6-diphenyl-3,4,9,10-tetrahydroacridine-1,8(2h,5h)-dione
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-06-01
description In the title compound, C33H27BrClNO4, the dihydropyridine ring adopts a flattened boat conformation. The molecular conformation is stabilized by an intramolecular O—H...O hydrogen bond, with an S(8) ring motif. In the crystal, O—H...O, C—H...O and C—H...Cl hydrogen bonds, and C—H...π interactions link the molecules, forming a three-dimensional network. In the acridinedione ring system, the two ring C atoms at the 2- and 3-positions, and the C atom at the 6-position and the atoms of the phenyl ring attached to the C atom at the 6-position are disordered over two sets of sites with occupancy ratios of 0.783 (5):0.217 (5) and 0.526 (18):0.474 (18), respectively.
url http://scripts.iucr.org/cgi-bin/paper?S1600536814010460
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