Crystal structure of 1,7,8,9-tetrachloro-4-(3,5-dichlorobenzyl)-10,10-dimethoxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione

In the title compound, C17H11Cl6NO4, the configuration of the cycloalkene skeleton is endo,cis. The benzene ring is twisted by 58.94 (8)° from the attached pyrrolidine ring. Two carbonyl groups play a key role in the crystal packing. A short intermolecular C...O distance of 3.017 (3) Å reveals that...

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Main Authors:	He Liu, Jia-liang Zhong, Wen-xia Sun, Yan-qing Gong, Li-hong Liu
Format:	Article
Language:	English
Published:	International Union of Crystallography 2015-01-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione biological activity cycloalkene skeleton dipole–dipole interactions hydrogen bonding
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989014025961

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record_format	Article
spelling	doaj-88b1ebe78c7a448c8e281b2042b63d4d2020-11-24T20:42:19ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-01-01711o14o1510.1107/S2056989014025961cv5477Crystal structure of 1,7,8,9-tetrachloro-4-(3,5-dichlorobenzyl)-10,10-dimethoxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dioneHe Liu0Jia-liang Zhong1Wen-xia Sun2Yan-qing Gong3Li-hong Liu4Beijing Chao-Yang Hospital, Capital Medical University, Beijing 100020, People's Republic of ChinaShanghai Institute of Pharmaceutical Industry, Shanghai 200040, People's Republic of ChinaShanghai Institute of Pharmaceutical Industry, Shanghai 200040, People's Republic of ChinaState Key Laboratory of Bio-Organic & Natural Products Chmemistry, Shanghai Institute of Organic Chemistry, CAS., Shanghai 200032, People's Republic of ChinaBeijing Chao-Yang Hospital, Capital Medical University, Beijing 100020, People's Republic of ChinaIn the title compound, C17H11Cl6NO4, the configuration of the cycloalkene skeleton is endo,cis. The benzene ring is twisted by 58.94 (8)° from the attached pyrrolidine ring. Two carbonyl groups play a key role in the crystal packing. A short intermolecular C...O distance of 3.017 (3) Å reveals that one carbonyl group is involved in dipole–dipole interactions, which link two adjacent enantiomers into an inversion dimer. Another carbonyl group provides an acceptor for the weak intermolecular C—H...O hydrogen bonds which link these dimers into layers parallel to (011).http://scripts.iucr.org/cgi-bin/paper?S2056989014025961crystal structuretricyclo[5.2.1.02,6]dec-8-ene-3,5-dionebiological activitycycloalkene skeletondipole–dipole interactionshydrogen bonding
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	He Liu Jia-liang Zhong Wen-xia Sun Yan-qing Gong Li-hong Liu
spellingShingle	He Liu Jia-liang Zhong Wen-xia Sun Yan-qing Gong Li-hong Liu Crystal structure of 1,7,8,9-tetrachloro-4-(3,5-dichlorobenzyl)-10,10-dimethoxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione Acta Crystallographica Section E: Crystallographic Communications crystal structure tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione biological activity cycloalkene skeleton dipole–dipole interactions hydrogen bonding
author_facet	He Liu Jia-liang Zhong Wen-xia Sun Yan-qing Gong Li-hong Liu
author_sort	He Liu
title	Crystal structure of 1,7,8,9-tetrachloro-4-(3,5-dichlorobenzyl)-10,10-dimethoxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
title_short	Crystal structure of 1,7,8,9-tetrachloro-4-(3,5-dichlorobenzyl)-10,10-dimethoxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
title_full	Crystal structure of 1,7,8,9-tetrachloro-4-(3,5-dichlorobenzyl)-10,10-dimethoxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
title_fullStr	Crystal structure of 1,7,8,9-tetrachloro-4-(3,5-dichlorobenzyl)-10,10-dimethoxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
title_full_unstemmed	Crystal structure of 1,7,8,9-tetrachloro-4-(3,5-dichlorobenzyl)-10,10-dimethoxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
title_sort	crystal structure of 1,7,8,9-tetrachloro-4-(3,5-dichlorobenzyl)-10,10-dimethoxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
publisher	International Union of Crystallography
series	Acta Crystallographica Section E: Crystallographic Communications
issn	2056-9890
publishDate	2015-01-01
description	In the title compound, C17H11Cl6NO4, the configuration of the cycloalkene skeleton is endo,cis. The benzene ring is twisted by 58.94 (8)° from the attached pyrrolidine ring. Two carbonyl groups play a key role in the crystal packing. A short intermolecular C...O distance of 3.017 (3) Å reveals that one carbonyl group is involved in dipole–dipole interactions, which link two adjacent enantiomers into an inversion dimer. Another carbonyl group provides an acceptor for the weak intermolecular C—H...O hydrogen bonds which link these dimers into layers parallel to (011).
topic	crystal structure tricyclo[5.2.1.02,6]dec-8-ene-3,5-dione biological activity cycloalkene skeleton dipole–dipole interactions hydrogen bonding
url	http://scripts.iucr.org/cgi-bin/paper?S2056989014025961
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Crystal structure of 1,7,8,9-tetrachloro-4-(3,5-dichlorobenzyl)-10,10-dimethoxy-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione

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