Bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvate

Bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvate

In the structure of the title compound, [Pd(C19H21N2P)2](PF6)2·2.85CH3CN, the two six-membered NHC-phosphane chelate rings form a distorted square-planar coordination geometry around the PdII atom, which lies 0.212 (1) Å above the coordination pl...

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Main Authors: A. Ahmida Aziza, Ulrich Flörke, Hans Egold, Gerald Henkel
Format: Article
Language:English
Published: International Union of Crystallography 2010-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681001319X
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spelling doaj-88f99aa7e82446059ffc79ba698a188d2020-11-24T21:52:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-05-01665m522m52210.1107/S160053681001319XBis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvateA. Ahmida AzizaUlrich FlörkeHans EgoldGerald HenkelIn the structure of the title compound, [Pd(C19H21N2P)2](PF6)2·2.85CH3CN, the two six-membered NHC-phosphane chelate rings form a distorted square-planar coordination geometry around the PdII atom, which lies 0.212 (1) Å above the coordination plane. The sum of the bond angles at PdII is 358.3°, with C—Pd—P bite angles of 84.03 (10) and 83.54 (9)°. The structure includes three acetonitrile solvent molecules, one with partial site occupation and one with severe disorder, which was eventually excluded from the refinement. http://scripts.iucr.org/cgi-bin/paper?S160053681001319X
collection DOAJ
language English
format Article
sources DOAJ
author A. Ahmida Aziza
Ulrich Flörke
Hans Egold
Gerald Henkel
spellingShingle A. Ahmida Aziza
Ulrich Flörke
Hans Egold
Gerald Henkel
Bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvate
Acta Crystallographica Section E
author_facet A. Ahmida Aziza
Ulrich Flörke
Hans Egold
Gerald Henkel
author_sort A. Ahmida Aziza
title Bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvate
title_short Bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvate
title_full Bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvate
title_fullStr Bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvate
title_full_unstemmed Bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvate
title_sort bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(ii) bis(hexafluoridophosphate) acetonitrile 2.85-solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-05-01
description In the structure of the title compound, [Pd(C19H21N2P)2](PF6)2·2.85CH3CN, the two six-membered NHC-phosphane chelate rings form a distorted square-planar coordination geometry around the PdII atom, which lies 0.212 (1) Å above the coordination plane. The sum of the bond angles at PdII is 358.3°, with C—Pd—P bite angles of 84.03 (10) and 83.54 (9)°. The structure includes three acetonitrile solvent molecules, one with partial site occupation and one with severe disorder, which was eventually excluded from the refinement.
url http://scripts.iucr.org/cgi-bin/paper?S160053681001319X
work_keys_str_mv AT aahmidaaziza bis12diphenylphosphinoethyl3ethylimidazol2ylidenepalladiumiibishexafluoridophosphateacetonitrile285solvate
AT ulrichflamp246rke bis12diphenylphosphinoethyl3ethylimidazol2ylidenepalladiumiibishexafluoridophosphateacetonitrile285solvate
AT hansegold bis12diphenylphosphinoethyl3ethylimidazol2ylidenepalladiumiibishexafluoridophosphateacetonitrile285solvate
AT geraldhenkel bis12diphenylphosphinoethyl3ethylimidazol2ylidenepalladiumiibishexafluoridophosphateacetonitrile285solvate
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