[5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)
The title compound, [Ni(C28H28N4)], crystallizes with two independent molecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043&...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812035726 |
| Summary: | The title compound, [Ni(C28H28N4)], crystallizes with two independent molecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043 Å for the first molecule and 0.026 Å for the molecule located on an inversion center. The average Ni—N bond lengths are 1.955 (2) and 1.956 (2) Å in the two molecules. The molecules form π–π dimers of intermediary strength with a mean plane separation of 3.36 (2) Å. |
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| ISSN: | 1600-5368 |