[5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)

[5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)

The title compound, [Ni(C28H28N4)], crystallizes with two independent molecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043&...

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Main Author: Mathias O. Senge
Format: Article
Language:English
Published: International Union of Crystallography 2012-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812035726
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spelling doaj-890321fecb0e44028e6c32d6a09d0de62020-11-25T02:00:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1191m119210.1107/S1600536812035726[5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)Mathias O. SengeThe title compound, [Ni(C28H28N4)], crystallizes with two independent molecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043 Å for the first molecule and 0.026 Å for the molecule located on an inversion center. The average Ni—N bond lengths are 1.955 (2) and 1.956 (2) Å in the two molecules. The molecules form π–π dimers of intermediary strength with a mean plane separation of 3.36 (2) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536812035726
collection DOAJ
language English
format Article
sources DOAJ
author Mathias O. Senge
spellingShingle Mathias O. Senge
[5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)
Acta Crystallographica Section E
author_facet Mathias O. Senge
author_sort Mathias O. Senge
title [5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)
title_short [5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)
title_full [5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)
title_fullStr [5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)
title_full_unstemmed [5,15-Bis(2-methylpropyl)porphyrinato]nickel(II)
title_sort [5,15-bis(2-methylpropyl)porphyrinato]nickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-09-01
description The title compound, [Ni(C28H28N4)], crystallizes with two independent molecules in the unit cell, one of which is located on an inversion center. Both macrocycles exhibit a planar conformation with average deviation from the least-squares-plane of the 24 macrocycle atoms of Δ24 = 0.043 Å for the first molecule and 0.026 Å for the molecule located on an inversion center. The average Ni—N bond lengths are 1.955 (2) and 1.956 (2) Å in the two molecules. The molecules form π–π dimers of intermediary strength with a mean plane separation of 3.36 (2) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812035726
work_keys_str_mv AT mathiasosenge 515bis2methylpropylporphyrinatonickelii
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