[(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)

[(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)

In the title complex, [Pt(SCN)2(C8H12)], the PtII ion lies in a square-planar coordination geometry defined by the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene and two S-bound SCN− anions. The complex is disposed about a mirror plane passing through the Pt atom and the SCN...

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Bibliographic Details
Main Author: Kwang Ha
Format: Article
Language:English
Published: International Union of Crystallography 2019-01-01
Series:IUCrData
Subjects:
crystal structure
platinum(II) complex
cycloocta-1,5-diene
thiocyanate
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314619001627
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spelling doaj-89778c2883564983a9e55aacea2cdd7d2020-11-24T23:21:23ZengInternational Union of CrystallographyIUCrData2414-31462019-01-0141x19016210.1107/S2414314619001627tk4054[(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)Kwang Ha0Chonnam National University, School of Chemical Engineering, Research Institute of Catalysis, Gwangju, Republic of KoreaIn the title complex, [Pt(SCN)2(C8H12)], the PtII ion lies in a square-planar coordination geometry defined by the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene and two S-bound SCN− anions. The complex is disposed about a mirror plane passing through the Pt atom and the SCN− ligands, and bisecting the cycloocta-1,5-diene molecule. The room-temperature crystal structure of the title complex was previously reported in the orthorhombic space group Pna21 [Musitu & Garcia-Blanco (1984). Acta Cryst. A40, C101]. The low-temperature structure presented herein represents a different (higher symmetry) orthorhombic space group Pnma whereby the PtII atom lies on a mirror plane, lacking in the earlier study.http://scripts.iucr.org/cgi-bin/paper?S2414314619001627crystal structureplatinum(II) complexcycloocta-1,5-dienethiocyanate
collection DOAJ
language English
format Article
sources DOAJ
author Kwang Ha
spellingShingle Kwang Ha
[(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)
IUCrData
crystal structure
platinum(II) complex
cycloocta-1,5-diene
thiocyanate
author_facet Kwang Ha
author_sort Kwang Ha
title [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)
title_short [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)
title_full [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)
title_fullStr [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)
title_full_unstemmed [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(thiocyanato-κS)platinum(II)
title_sort [(1,2,5,6-η)-cycloocta-1,5-diene]bis(thiocyanato-κs)platinum(ii)
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2019-01-01
description In the title complex, [Pt(SCN)2(C8H12)], the PtII ion lies in a square-planar coordination geometry defined by the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene and two S-bound SCN− anions. The complex is disposed about a mirror plane passing through the Pt atom and the SCN− ligands, and bisecting the cycloocta-1,5-diene molecule. The room-temperature crystal structure of the title complex was previously reported in the orthorhombic space group Pna21 [Musitu & Garcia-Blanco (1984). Acta Cryst. A40, C101]. The low-temperature structure presented herein represents a different (higher symmetry) orthorhombic space group Pnma whereby the PtII atom lies on a mirror plane, lacking in the earlier study.
topic crystal structure
platinum(II) complex
cycloocta-1,5-diene
thiocyanate
url http://scripts.iucr.org/cgi-bin/paper?S2414314619001627
work_keys_str_mv AT kwangha 1256ēcycloocta15dienebisthiocyanatoksplatinumii
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