Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thiophen-2-yl)propanone

The title compound, C11H9NOS, was obtained in an improved yield compared to previous literature methods. The molecule is essentially planar with a maximum deviation of 0.085 Å from the mean plane through all non-H atoms. There is directive intermolecular hydrogen bonding in the form of N—H...O hydro...

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Main Authors:	Dáire Gibbons, Ganapathi Emandi, Mathias O. Senge
Format:	Article
Language:	English
Published:	International Union of Crystallography 2018-10-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure thiophene pyrrole BODIPY aza-BODIPY
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989018012331

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record_format	Article
spelling	doaj-89a21a135e264a3c9a5d45e9272eb8752020-11-25T00:41:05ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-10-0174101463146610.1107/S2056989018012331tx2008Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thiophen-2-yl)propanoneDáire Gibbons0Ganapathi Emandi1Mathias O. Senge2School of Chemistry, Trinity Biomedical Sciences Institute, 152–160 Pearse Street, Trinity College Dublin, The University of Dublin, Dublin 2, IrelandSchool of Chemistry, Trinity Biomedical Sciences Institute, 152–160 Pearse Street, Trinity College Dublin, The University of Dublin, Dublin 2, IrelandSchool of Chemistry, Trinity Biomedical Sciences Institute, 152–160 Pearse Street, Trinity College Dublin, The University of Dublin, Dublin 2, IrelandThe title compound, C11H9NOS, was obtained in an improved yield compared to previous literature methods. The molecule is essentially planar with a maximum deviation of 0.085 Å from the mean plane through all non-H atoms. There is directive intermolecular hydrogen bonding in the form of N—H...O hydrogen bonds with a distance of 2.889 (3) Å between the pyrrole amine and the ketone carbonyl O atom. The resulting hydrogen-bonding network defines a ribbon parallel to the a axis. These ribbons form offset stacks along the b axis.http://scripts.iucr.org/cgi-bin/paper?S2056989018012331crystal structurethiophenepyrroleBODIPYaza-BODIPY
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Dáire Gibbons Ganapathi Emandi Mathias O. Senge
spellingShingle	Dáire Gibbons Ganapathi Emandi Mathias O. Senge Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thiophen-2-yl)propanone Acta Crystallographica Section E: Crystallographic Communications crystal structure thiophene pyrrole BODIPY aza-BODIPY
author_facet	Dáire Gibbons Ganapathi Emandi Mathias O. Senge
author_sort	Dáire Gibbons
title	Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thiophen-2-yl)propanone
title_short	Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thiophen-2-yl)propanone
title_full	Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thiophen-2-yl)propanone
title_fullStr	Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thiophen-2-yl)propanone
title_full_unstemmed	Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thiophen-2-yl)propanone
title_sort	crystal structure and synthesis of 3-(1h-pyrrol-2-yl)-1-(thiophen-2-yl)propanone
publisher	International Union of Crystallography
series	Acta Crystallographica Section E: Crystallographic Communications
issn	2056-9890
publishDate	2018-10-01
description	The title compound, C11H9NOS, was obtained in an improved yield compared to previous literature methods. The molecule is essentially planar with a maximum deviation of 0.085 Å from the mean plane through all non-H atoms. There is directive intermolecular hydrogen bonding in the form of N—H...O hydrogen bonds with a distance of 2.889 (3) Å between the pyrrole amine and the ketone carbonyl O atom. The resulting hydrogen-bonding network defines a ribbon parallel to the a axis. These ribbons form offset stacks along the b axis.
topic	crystal structure thiophene pyrrole BODIPY aza-BODIPY
url	http://scripts.iucr.org/cgi-bin/paper?S2056989018012331
work_keys_str_mv	AT dairegibbons crystalstructureandsynthesisof31hpyrrol2yl1thiophen2ylpropanone AT ganapathiemandi crystalstructureandsynthesisof31hpyrrol2yl1thiophen2ylpropanone AT mathiasosenge crystalstructureandsynthesisof31hpyrrol2yl1thiophen2ylpropanone
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Crystal structure and synthesis of 3-(1H-pyrrol-2-yl)-1-(thiophen-2-yl)propanone

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