Ru-fe3o4-containing Polymeric Catalysts for Cellulose Hydrogenolysis

Ru-fe3o4-containing Polymeric Catalysts for Cellulose Hydrogenolysis

In this paper, a novel catalysts on the base of hypercrosslinked polystyrene (HPS) with magnetic properties are proposed for the one-pot processes of the cellulose conversion into ethylene glycol (EG) and propylene glycol (PG). Synthesized magnetically recoverable supports and catalysts were charact...

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Main Authors: Oleg Manaenkov, Olga Kislitsa, Ekaterina Ratkevich, Valentina Matveeva, Mikhail Sulman, Esther Sulman
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2019-05-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/9779
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spelling doaj-89b84178d36042ccb43ef4f8fdbbec852021-02-16T21:07:42ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162019-05-017410.3303/CET1974014Ru-fe3o4-containing Polymeric Catalysts for Cellulose HydrogenolysisOleg ManaenkovOlga KislitsaEkaterina RatkevichValentina MatveevaMikhail SulmanEsther SulmanIn this paper, a novel catalysts on the base of hypercrosslinked polystyrene (HPS) with magnetic properties are proposed for the one-pot processes of the cellulose conversion into ethylene glycol (EG) and propylene glycol (PG). Synthesized magnetically recoverable supports and catalysts were characterized by different physical-chemical methods. The magnetic properties of the supports Fe3O4/HPS MN270 and the corresponding catalysts were studied. The use of this catalyst in the process of microcrystalline cellulose hydrogenolysis in subcritical water allows PG and EG selectivities of 20.0 and 22.6%, respectively, at 100% of cellulose conversion.https://www.cetjournal.it/index.php/cet/article/view/9779
collection DOAJ
language English
format Article
sources DOAJ
author Oleg Manaenkov
Olga Kislitsa
Ekaterina Ratkevich
Valentina Matveeva
Mikhail Sulman
Esther Sulman
spellingShingle Oleg Manaenkov
Olga Kislitsa
Ekaterina Ratkevich
Valentina Matveeva
Mikhail Sulman
Esther Sulman
Ru-fe3o4-containing Polymeric Catalysts for Cellulose Hydrogenolysis
Chemical Engineering Transactions
author_facet Oleg Manaenkov
Olga Kislitsa
Ekaterina Ratkevich
Valentina Matveeva
Mikhail Sulman
Esther Sulman
author_sort Oleg Manaenkov
title Ru-fe3o4-containing Polymeric Catalysts for Cellulose Hydrogenolysis
title_short Ru-fe3o4-containing Polymeric Catalysts for Cellulose Hydrogenolysis
title_full Ru-fe3o4-containing Polymeric Catalysts for Cellulose Hydrogenolysis
title_fullStr Ru-fe3o4-containing Polymeric Catalysts for Cellulose Hydrogenolysis
title_full_unstemmed Ru-fe3o4-containing Polymeric Catalysts for Cellulose Hydrogenolysis
title_sort ru-fe3o4-containing polymeric catalysts for cellulose hydrogenolysis
publisher AIDIC Servizi S.r.l.
series Chemical Engineering Transactions
issn 2283-9216
publishDate 2019-05-01
description In this paper, a novel catalysts on the base of hypercrosslinked polystyrene (HPS) with magnetic properties are proposed for the one-pot processes of the cellulose conversion into ethylene glycol (EG) and propylene glycol (PG). Synthesized magnetically recoverable supports and catalysts were characterized by different physical-chemical methods. The magnetic properties of the supports Fe3O4/HPS MN270 and the corresponding catalysts were studied. The use of this catalyst in the process of microcrystalline cellulose hydrogenolysis in subcritical water allows PG and EG selectivities of 20.0 and 22.6%, respectively, at 100% of cellulose conversion.
url https://www.cetjournal.it/index.php/cet/article/view/9779
work_keys_str_mv AT olegmanaenkov rufe3o4containingpolymericcatalystsforcellulosehydrogenolysis
AT olgakislitsa rufe3o4containingpolymericcatalystsforcellulosehydrogenolysis
AT ekaterinaratkevich rufe3o4containingpolymericcatalystsforcellulosehydrogenolysis
AT valentinamatveeva rufe3o4containingpolymericcatalystsforcellulosehydrogenolysis
AT mikhailsulman rufe3o4containingpolymericcatalystsforcellulosehydrogenolysis
AT esthersulman rufe3o4containingpolymericcatalystsforcellulosehydrogenolysis
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