Global distributions of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN retrieved from MIPAS reduced spectral resolution measurements

Vertical profiles of mixing ratios of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN were retrieved from MIPAS reduced spectral resolution nominal mode limb emission measurements. The retrieval strategy follows that of the analysi...

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Main Authors: T. von Clarmann, G. Stiller, A. Linden, S. Kellmann, U. Grabowski, M. Höpfner, N. Glatthor, A. Wiegele
Format: Article
Language:English
Published: Copernicus Publications 2012-04-01
Series:Atmospheric Measurement Techniques
Online Access:http://www.atmos-meas-tech.net/5/723/2012/amt-5-723-2012.pdf
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spelling doaj-89bc0981c0e9420c8e857104911d5c8b2020-11-24T22:48:53ZengCopernicus PublicationsAtmospheric Measurement Techniques1867-13811867-85482012-04-015472373410.5194/amt-5-723-2012Global distributions of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN retrieved from MIPAS reduced spectral resolution measurementsT. von ClarmannG. StillerA. LindenS. KellmannU. GrabowskiM. HöpfnerN. GlatthorA. WiegeleVertical profiles of mixing ratios of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN were retrieved from MIPAS reduced spectral resolution nominal mode limb emission measurements. The retrieval strategy follows that of the analysis of MIPAS high resolution measurements, with occasional adjustments to cope with the reduced spectral resolution under which MIPAS is operated since 2005. MIPAS measurements from January 2005 to January 2010 have been analyzed with special emphasis on October 2007. Largest mixing ratios are found in the troposphere, and reach 1.2 ppbv for C<sub>2</sub>H<sub>6</sub>, 1 ppbv for HCN, 600 pptv for PAN, and 450 pptv for C<sub>2</sub>H<sub>2</sub>. The estimated precisions in case of significantly enhanced mixing ratios (including measurement noise and propagation of uncertain parameters randomly varying in the time domain) and altitude resolution are typically 10%, 3–4.5 km for C<sub>2</sub>H<sub>6</sub>, 15%, 4–6 km for HCN, 6%, 2.5–3.5 km for PAN, and 7%, 2.5–4 km for C<sub>2</sub>H<sub>2</sub>.http://www.atmos-meas-tech.net/5/723/2012/amt-5-723-2012.pdf
collection DOAJ
language English
format Article
sources DOAJ
author T. von Clarmann
G. Stiller
A. Linden
S. Kellmann
U. Grabowski
M. Höpfner
N. Glatthor
A. Wiegele
spellingShingle T. von Clarmann
G. Stiller
A. Linden
S. Kellmann
U. Grabowski
M. Höpfner
N. Glatthor
A. Wiegele
Global distributions of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN retrieved from MIPAS reduced spectral resolution measurements
Atmospheric Measurement Techniques
author_facet T. von Clarmann
G. Stiller
A. Linden
S. Kellmann
U. Grabowski
M. Höpfner
N. Glatthor
A. Wiegele
author_sort T. von Clarmann
title Global distributions of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN retrieved from MIPAS reduced spectral resolution measurements
title_short Global distributions of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN retrieved from MIPAS reduced spectral resolution measurements
title_full Global distributions of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN retrieved from MIPAS reduced spectral resolution measurements
title_fullStr Global distributions of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN retrieved from MIPAS reduced spectral resolution measurements
title_full_unstemmed Global distributions of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN retrieved from MIPAS reduced spectral resolution measurements
title_sort global distributions of c<sub>2</sub>h<sub>6</sub>, c<sub>2</sub>h<sub>2</sub>, hcn, and pan retrieved from mipas reduced spectral resolution measurements
publisher Copernicus Publications
series Atmospheric Measurement Techniques
issn 1867-1381
1867-8548
publishDate 2012-04-01
description Vertical profiles of mixing ratios of C<sub>2</sub>H<sub>6</sub>, C<sub>2</sub>H<sub>2</sub>, HCN, and PAN were retrieved from MIPAS reduced spectral resolution nominal mode limb emission measurements. The retrieval strategy follows that of the analysis of MIPAS high resolution measurements, with occasional adjustments to cope with the reduced spectral resolution under which MIPAS is operated since 2005. MIPAS measurements from January 2005 to January 2010 have been analyzed with special emphasis on October 2007. Largest mixing ratios are found in the troposphere, and reach 1.2 ppbv for C<sub>2</sub>H<sub>6</sub>, 1 ppbv for HCN, 600 pptv for PAN, and 450 pptv for C<sub>2</sub>H<sub>2</sub>. The estimated precisions in case of significantly enhanced mixing ratios (including measurement noise and propagation of uncertain parameters randomly varying in the time domain) and altitude resolution are typically 10%, 3–4.5 km for C<sub>2</sub>H<sub>6</sub>, 15%, 4–6 km for HCN, 6%, 2.5–3.5 km for PAN, and 7%, 2.5–4 km for C<sub>2</sub>H<sub>2</sub>.
url http://www.atmos-meas-tech.net/5/723/2012/amt-5-723-2012.pdf
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