5,10,15,20-Tetrakis(3,5-difluorophenyl)porphyrin

5,10,15,20-Tetrakis(3,5-difluorophenyl)porphyrin

The crystal structure of the title compound, C44H22F8N4, shows an unusual non-planar geometry of the porphyrin ring although the molecule is free of steric crowding around the periphery of the macrocycle. The molecular packing exhibits weak intermolecular hydrogen bonding (C—H...F) and C&a...

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Bibliographic Details
Main Authors: P. Bhyrappa, V. Velkannan, B. Varghese
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807062782
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spelling doaj-89d3e255d70544adb969fba71d252dca2020-11-25T00:17:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641o190o19010.1107/S16005368070627825,10,15,20-Tetrakis(3,5-difluorophenyl)porphyrinP. BhyrappaV. VelkannanB. VargheseThe crystal structure of the title compound, C44H22F8N4, shows an unusual non-planar geometry of the porphyrin ring although the molecule is free of steric crowding around the periphery of the macrocycle. The molecular packing exhibits weak intermolecular hydrogen bonding (C—H...F) and C—H...π interactions. The molecular symmetry is overline 4.http://scripts.iucr.org/cgi-bin/paper?S1600536807062782
collection DOAJ
language English
format Article
sources DOAJ
author P. Bhyrappa
V. Velkannan
B. Varghese
spellingShingle P. Bhyrappa
V. Velkannan
B. Varghese
5,10,15,20-Tetrakis(3,5-difluorophenyl)porphyrin
Acta Crystallographica Section E
author_facet P. Bhyrappa
V. Velkannan
B. Varghese
author_sort P. Bhyrappa
title 5,10,15,20-Tetrakis(3,5-difluorophenyl)porphyrin
title_short 5,10,15,20-Tetrakis(3,5-difluorophenyl)porphyrin
title_full 5,10,15,20-Tetrakis(3,5-difluorophenyl)porphyrin
title_fullStr 5,10,15,20-Tetrakis(3,5-difluorophenyl)porphyrin
title_full_unstemmed 5,10,15,20-Tetrakis(3,5-difluorophenyl)porphyrin
title_sort 5,10,15,20-tetrakis(3,5-difluorophenyl)porphyrin
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description The crystal structure of the title compound, C44H22F8N4, shows an unusual non-planar geometry of the porphyrin ring although the molecule is free of steric crowding around the periphery of the macrocycle. The molecular packing exhibits weak intermolecular hydrogen bonding (C—H...F) and C—H...π interactions. The molecular symmetry is overline 4.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807062782
work_keys_str_mv AT pbhyrappa 5101520tetrakis35difluorophenylporphyrin
AT vvelkannan 5101520tetrakis35difluorophenylporphyrin
AT bvarghese 5101520tetrakis35difluorophenylporphyrin
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