Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation

Hydroformylation of 1,2-disubstituted alkenes usually occurs at the α position of the directing heteroatom. Here, the authors report the asymmetric rhodium-catalyzed hydroformylation of 1,2-disubstituted alkenylsilanes with excellent regioselectivity at the β position (relative to the silicon hetero...

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Main Authors:	Cai You, Xiuxiu Li, Yuhong Yang, Yu-Sheng Yang, Xuefeng Tan, Shuailong Li, Biao Wei, Hui Lv, Lung-Wa Chung, Xumu Zhang
Format:	Article
Language:	English
Published:	Nature Publishing Group 2018-05-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-018-04277-7

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spelling	doaj-8a8889051f1e44aa88f300938dd4c0c12021-05-11T09:22:20ZengNature Publishing GroupNature Communications2041-17232018-05-01911910.1038/s41467-018-04277-7Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylationCai You0Xiuxiu Li1Yuhong Yang2Yu-Sheng Yang3Xuefeng Tan4Shuailong Li5Biao Wei6Hui Lv7Lung-Wa Chung8Xumu Zhang9Key Laboratory of Biomedical Polymers of Ministry of Education & College of Chemistry and Molecular Sciences, Wuhan UniversityKey Laboratory of Biomedical Polymers of Ministry of Education & College of Chemistry and Molecular Sciences, Wuhan UniversityDepartment of Chemistry, Southern University of Science and Technology, ShenzhenKey Laboratory of Biomedical Polymers of Ministry of Education & College of Chemistry and Molecular Sciences, Wuhan UniversityDepartment of Chemistry, Southern University of Science and Technology, ShenzhenKey Laboratory of Biomedical Polymers of Ministry of Education & College of Chemistry and Molecular Sciences, Wuhan UniversityKey Laboratory of Biomedical Polymers of Ministry of Education & College of Chemistry and Molecular Sciences, Wuhan UniversityKey Laboratory of Biomedical Polymers of Ministry of Education & College of Chemistry and Molecular Sciences, Wuhan UniversityDepartment of Chemistry, Southern University of Science and Technology, ShenzhenKey Laboratory of Biomedical Polymers of Ministry of Education & College of Chemistry and Molecular Sciences, Wuhan UniversityHydroformylation of 1,2-disubstituted alkenes usually occurs at the α position of the directing heteroatom. Here, the authors report the asymmetric rhodium-catalyzed hydroformylation of 1,2-disubstituted alkenylsilanes with excellent regioselectivity at the β position (relative to the silicon heteroatom) and enantioselectivity.https://doi.org/10.1038/s41467-018-04277-7
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Cai You Xiuxiu Li Yuhong Yang Yu-Sheng Yang Xuefeng Tan Shuailong Li Biao Wei Hui Lv Lung-Wa Chung Xumu Zhang
spellingShingle	Cai You Xiuxiu Li Yuhong Yang Yu-Sheng Yang Xuefeng Tan Shuailong Li Biao Wei Hui Lv Lung-Wa Chung Xumu Zhang Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation Nature Communications
author_facet	Cai You Xiuxiu Li Yuhong Yang Yu-Sheng Yang Xuefeng Tan Shuailong Li Biao Wei Hui Lv Lung-Wa Chung Xumu Zhang
author_sort	Cai You
title	Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
title_short	Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
title_full	Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
title_fullStr	Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
title_full_unstemmed	Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
title_sort	silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2018-05-01
description	Hydroformylation of 1,2-disubstituted alkenes usually occurs at the α position of the directing heteroatom. Here, the authors report the asymmetric rhodium-catalyzed hydroformylation of 1,2-disubstituted alkenylsilanes with excellent regioselectivity at the β position (relative to the silicon heteroatom) and enantioselectivity.
url	https://doi.org/10.1038/s41467-018-04277-7
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Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation

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