Beyond Gibbs-Boltzmann-Shannon: General Entropies -- The Gibbs-Lorentzian Example

We propose a generalisation of Gibbs' statistical mechanics into the domain of non-negligible phase space correlations. Derived are the probability distribution and entropy as a generalised ensemble average, replacing Gibbs-Boltzmann-Shannon's entropy definition enabling construction of...

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Bibliographic Details
Main Authors: Rudolf A. Treumann, Wolfgang eBaumjohann
Format: Article
Language:English
Published: Frontiers Media S.A. 2014-08-01
Series:Frontiers in Physics
Subjects:
Online Access:http://journal.frontiersin.org/Journal/10.3389/fphy.2014.00049/full
Description
Summary:We propose a generalisation of Gibbs' statistical mechanics into the domain of non-negligible phase space correlations. Derived are the probability distribution and entropy as a generalised ensemble average, replacing Gibbs-Boltzmann-Shannon's entropy definition enabling construction of new forms of statistical mechanics. The general entropy may also be of importance in information theory and data analysis. Application to generalised Lorentzian phase space elements yields the Gibbs-Lorentzian power law probability distribution and statistical mechanics. The corresponding Boltzmann, Fermi and Bose-Einstein distributions are found. They apply only to finite temperature states including correlations. As a by-product any negative absolute temperatures are categorically excluded, supporting a recent ``no-negative $T$ claim.
ISSN:2296-424X