1-Bromo-1′-(diphenylthiophosphoryl)ferrocene

1-Bromo-1′-(diphenylthiophosphoryl)ferrocene

The title compound, [Fe(C5H4Br)(C17H14PS)], crystallizes with two practically undistiguishable molecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1′-diyl units exhibit a regular geometry with negligible tilting and balanced Fe&#8...

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Main Authors: Petr Štěpnička, Jiří Schulz, Ivana Císařová
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809036459
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spelling doaj-8aaafd0912d844c7a5dbbb8e27c6e2af2020-11-25T02:43:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510m1210m121010.1107/S16005368090364591-Bromo-1′-(diphenylthiophosphoryl)ferrocenePetr ŠtěpničkaJiří SchulzIvana CísařováThe title compound, [Fe(C5H4Br)(C17H14PS)], crystallizes with two practically undistiguishable molecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1′-diyl units exhibit a regular geometry with negligible tilting and balanced Fe–ring centroid distances, and with the attached substituents assuming conformations close to ideal synclinal eclipsed. http://scripts.iucr.org/cgi-bin/paper?S1600536809036459
collection DOAJ
language English
format Article
sources DOAJ
author Petr Štěpnička
Jiří Schulz
Ivana Císařová
spellingShingle Petr Štěpnička
Jiří Schulz
Ivana Císařová
1-Bromo-1′-(diphenylthiophosphoryl)ferrocene
Acta Crystallographica Section E
author_facet Petr Štěpnička
Jiří Schulz
Ivana Císařová
author_sort Petr Štěpnička
title 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene
title_short 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene
title_full 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene
title_fullStr 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene
title_full_unstemmed 1-Bromo-1′-(diphenylthiophosphoryl)ferrocene
title_sort 1-bromo-1′-(diphenylthiophosphoryl)ferrocene
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-10-01
description The title compound, [Fe(C5H4Br)(C17H14PS)], crystallizes with two practically undistiguishable molecules in the asymmetric unit, which are related by a non-space-group inversion. The ferrocene-1,1′-diyl units exhibit a regular geometry with negligible tilting and balanced Fe–ring centroid distances, and with the attached substituents assuming conformations close to ideal synclinal eclipsed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809036459
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AT ivanacamp237saamp345ovamp225 1bromo1amp8242diphenylthiophosphorylferrocene
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