Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review
Energy storage materials are finding increasing applications in our daily lives, for devices such as mobile phones and electric vehicles. Current commercial batteries use flammable liquid electrolytes, which are unsafe, toxic, and environmentally unfriendly with low chemical stability. Recently, sol...
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doaj-8ab2ad0427144a6da28e0deb0ffec9632020-11-25T03:35:04ZengMDPI AGNanomaterials2079-49912020-08-01101606160610.3390/nano10081606Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A ReviewMogalahalli V. Reddy0Christian M. Julien1Alain Mauger2Karim Zaghib3Centre of Excellence in Transportation Electrification and Energy Storage (CETEES), Institute of Research Hydro-Québec, 1806, Lionel-Boulet Blvd., Varennes, QC J3X 1S1, CanadaInstitut de Minéralogie, de Physique des Matériaux et de Cosmochimie (IMPMC), Sorbonne Université, UMR-CNRS 7590, 4 place Jussieu, 75252 Paris, FranceInstitut de Minéralogie, de Physique des Matériaux et de Cosmochimie (IMPMC), Sorbonne Université, UMR-CNRS 7590, 4 place Jussieu, 75252 Paris, FranceDepartment of Mining and Materials Engineering, McGill University, Wong Building, 3610 University Street, Montreal, QC H3A OC5, CanadaEnergy storage materials are finding increasing applications in our daily lives, for devices such as mobile phones and electric vehicles. Current commercial batteries use flammable liquid electrolytes, which are unsafe, toxic, and environmentally unfriendly with low chemical stability. Recently, solid electrolytes have been extensively studied as alternative electrolytes to address these shortcomings. Herein, we report the early history, synthesis and characterization, mechanical properties, and Li<sup>+</sup> ion transport mechanisms of inorganic sulfide and oxide electrolytes. Furthermore, we highlight the importance of the fabrication technology and experimental conditions, such as the effects of pressure and operating parameters, on the electrochemical performance of all-solid-state Li batteries. In particular, we emphasize promising electrolyte systems based on sulfides and argyrodites, such as LiPS<sub>5</sub>Cl and β-Li<sub>3</sub>PS<sub>4</sub>, oxide electrolytes, bare and doped Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> garnet, NASICON-type structures, and perovskite electrolyte materials. Moreover, we discuss the present and future challenges that all-solid-state batteries face for large-scale industrial applications.https://www.mdpi.com/2079-4991/10/8/1606electrolytessolid statenanomaterialssulfidesoxidesall-solid-state batteries |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Mogalahalli V. Reddy Christian M. Julien Alain Mauger Karim Zaghib |
spellingShingle |
Mogalahalli V. Reddy Christian M. Julien Alain Mauger Karim Zaghib Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review Nanomaterials electrolytes solid state nanomaterials sulfides oxides all-solid-state batteries |
author_facet |
Mogalahalli V. Reddy Christian M. Julien Alain Mauger Karim Zaghib |
author_sort |
Mogalahalli V. Reddy |
title |
Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review |
title_short |
Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review |
title_full |
Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review |
title_fullStr |
Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review |
title_full_unstemmed |
Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review |
title_sort |
sulfide and oxide inorganic solid electrolytes for all-solid-state li batteries: a review |
publisher |
MDPI AG |
series |
Nanomaterials |
issn |
2079-4991 |
publishDate |
2020-08-01 |
description |
Energy storage materials are finding increasing applications in our daily lives, for devices such as mobile phones and electric vehicles. Current commercial batteries use flammable liquid electrolytes, which are unsafe, toxic, and environmentally unfriendly with low chemical stability. Recently, solid electrolytes have been extensively studied as alternative electrolytes to address these shortcomings. Herein, we report the early history, synthesis and characterization, mechanical properties, and Li<sup>+</sup> ion transport mechanisms of inorganic sulfide and oxide electrolytes. Furthermore, we highlight the importance of the fabrication technology and experimental conditions, such as the effects of pressure and operating parameters, on the electrochemical performance of all-solid-state Li batteries. In particular, we emphasize promising electrolyte systems based on sulfides and argyrodites, such as LiPS<sub>5</sub>Cl and β-Li<sub>3</sub>PS<sub>4</sub>, oxide electrolytes, bare and doped Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> garnet, NASICON-type structures, and perovskite electrolyte materials. Moreover, we discuss the present and future challenges that all-solid-state batteries face for large-scale industrial applications. |
topic |
electrolytes solid state nanomaterials sulfides oxides all-solid-state batteries |
url |
https://www.mdpi.com/2079-4991/10/8/1606 |
work_keys_str_mv |
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