Recent Advances in TiO<sub>2</sub>-Based Photocatalysts for Reduction of CO<sub>2</sub> to Fuels
Titanium dioxide (TiO<sub>2</sub>) has attracted increasing attention as a candidate for the photocatalytic reduction of carbon dioxide (CO<sub>2</sub>) to convert anthropogenic CO<sub>2</sub> gas into fuels combined with storage of intermittent and renewable sola...
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doaj-8b061af0a0124aa291ec08d8b486a83e2020-11-25T02:05:27ZengMDPI AGNanomaterials2079-49912020-02-0110233710.3390/nano10020337nano10020337Recent Advances in TiO<sub>2</sub>-Based Photocatalysts for Reduction of CO<sub>2</sub> to FuelsThang Phan Nguyen0Dang Le Tri Nguyen1Van-Huy Nguyen2Thu-Ha Le3Dai-Viet N. Vo4Quang Thang Trinh5Sa-Rang Bae6Sang Youn Chae7Soo Young Kim8Quyet Van Le9Laboratory of Advanced Materials Chemistry, Advanced Institute of Materials Science, Ton Duc Thang University, Ho Chi Minh City 700000, VietnamInstitute of Research and Development, Duy Tan University, Da Nang 550000, VietnamKey Laboratory of Advanced Materials for Energy and Environmental Applications, Lac Hong University, Bien Hoa 810000, VietnamFaculty of Materials Technology, Ho Chi Minh City University of Technology (HCMUT), Vietnam National University–Ho Chi Minh City (VNU–HCM), 268 Ly Thuong Kiet, District 10, Ho Chi Minh City 700000, VietnamCenter of Excellence for Green Energy and Environmental Nanomaterials (CE@GrEEN), Nguyen Tat Thanh University, 300A Nguyen Tat Thanh, District 4, Ho Chi Minh City 755414, VietnamCambridge Centre for Advanced Research and Education in Singapore (CARES), Campus for Research Excellence and Technological Enterprise (CREATE), 1 Create Way, Singapore 138602, SingaporeDepartment of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, KoreaDepartment of Materials Science, Institute for Surface Science and Corrosion, University of Erlangen-Nuremberg, Martensstrasse 7, 91058 Erlangen, GermanyDepartment of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, KoreaInstitute of Research and Development, Duy Tan University, Da Nang 550000, VietnamTitanium dioxide (TiO<sub>2</sub>) has attracted increasing attention as a candidate for the photocatalytic reduction of carbon dioxide (CO<sub>2</sub>) to convert anthropogenic CO<sub>2</sub> gas into fuels combined with storage of intermittent and renewable solar energy in forms of chemical bonds for closing the carbon cycle. However, pristine TiO<sub>2</sub> possesses a large band gap (3.2 eV), fast recombination of electrons and holes, and low selectivity for the photoreduction of CO<sub>2</sub>. Recently, considerable progress has been made in the improvement of the performance of TiO<sub>2</sub> photocatalysts for CO<sub>2</sub> reduction. In this review, we first discuss the fundamentals of and challenges in CO<sub>2</sub> photoreduction on TiO<sub>2</sub>-based catalysts. Next, the recently emerging progress and advances in TiO<sub>2</sub> nanostructured and hybrid materials for overcoming the mentioned obstacles to achieve high light-harvesting capability, improved adsorption and activation of CO<sub>2</sub>, excellent photocatalytic activity, the ability to impede the recombination of electrons-holes pairs, and efficient suppression of hydrogen evolution are discussed. In addition, approaches and strategies for improvements in TiO<sub>2</sub>-based photocatalysts and their working mechanisms are thoroughly summarized and analyzed. Lastly, the current challenges and prospects of CO<sub>2</sub> photocatalytic reactions on TiO<sub>2</sub>-based catalysts are also presented.https://www.mdpi.com/2079-4991/10/2/337photocatalysiscarbon dioxide reductiontio<sub>2</sub>-based photocatalystshigh efficiency |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Thang Phan Nguyen Dang Le Tri Nguyen Van-Huy Nguyen Thu-Ha Le Dai-Viet N. Vo Quang Thang Trinh Sa-Rang Bae Sang Youn Chae Soo Young Kim Quyet Van Le |
spellingShingle |
Thang Phan Nguyen Dang Le Tri Nguyen Van-Huy Nguyen Thu-Ha Le Dai-Viet N. Vo Quang Thang Trinh Sa-Rang Bae Sang Youn Chae Soo Young Kim Quyet Van Le Recent Advances in TiO<sub>2</sub>-Based Photocatalysts for Reduction of CO<sub>2</sub> to Fuels Nanomaterials photocatalysis carbon dioxide reduction tio<sub>2</sub>-based photocatalysts high efficiency |
author_facet |
Thang Phan Nguyen Dang Le Tri Nguyen Van-Huy Nguyen Thu-Ha Le Dai-Viet N. Vo Quang Thang Trinh Sa-Rang Bae Sang Youn Chae Soo Young Kim Quyet Van Le |
author_sort |
Thang Phan Nguyen |
title |
Recent Advances in TiO<sub>2</sub>-Based Photocatalysts for Reduction of CO<sub>2</sub> to Fuels |
title_short |
Recent Advances in TiO<sub>2</sub>-Based Photocatalysts for Reduction of CO<sub>2</sub> to Fuels |
title_full |
Recent Advances in TiO<sub>2</sub>-Based Photocatalysts for Reduction of CO<sub>2</sub> to Fuels |
title_fullStr |
Recent Advances in TiO<sub>2</sub>-Based Photocatalysts for Reduction of CO<sub>2</sub> to Fuels |
title_full_unstemmed |
Recent Advances in TiO<sub>2</sub>-Based Photocatalysts for Reduction of CO<sub>2</sub> to Fuels |
title_sort |
recent advances in tio<sub>2</sub>-based photocatalysts for reduction of co<sub>2</sub> to fuels |
publisher |
MDPI AG |
series |
Nanomaterials |
issn |
2079-4991 |
publishDate |
2020-02-01 |
description |
Titanium dioxide (TiO<sub>2</sub>) has attracted increasing attention as a candidate for the photocatalytic reduction of carbon dioxide (CO<sub>2</sub>) to convert anthropogenic CO<sub>2</sub> gas into fuels combined with storage of intermittent and renewable solar energy in forms of chemical bonds for closing the carbon cycle. However, pristine TiO<sub>2</sub> possesses a large band gap (3.2 eV), fast recombination of electrons and holes, and low selectivity for the photoreduction of CO<sub>2</sub>. Recently, considerable progress has been made in the improvement of the performance of TiO<sub>2</sub> photocatalysts for CO<sub>2</sub> reduction. In this review, we first discuss the fundamentals of and challenges in CO<sub>2</sub> photoreduction on TiO<sub>2</sub>-based catalysts. Next, the recently emerging progress and advances in TiO<sub>2</sub> nanostructured and hybrid materials for overcoming the mentioned obstacles to achieve high light-harvesting capability, improved adsorption and activation of CO<sub>2</sub>, excellent photocatalytic activity, the ability to impede the recombination of electrons-holes pairs, and efficient suppression of hydrogen evolution are discussed. In addition, approaches and strategies for improvements in TiO<sub>2</sub>-based photocatalysts and their working mechanisms are thoroughly summarized and analyzed. Lastly, the current challenges and prospects of CO<sub>2</sub> photocatalytic reactions on TiO<sub>2</sub>-based catalysts are also presented. |
topic |
photocatalysis carbon dioxide reduction tio<sub>2</sub>-based photocatalysts high efficiency |
url |
https://www.mdpi.com/2079-4991/10/2/337 |
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