Bis(1-ferrocenylethanone oximato)triphenylantimony(V)
In the title compound, [Fe2Sb(C5H5)2(C6H5)3(C7H7NO)2] or [Sb(C6H5)3{Fe(C5H5)(C7H7NO)}2], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oximate ligands in axial positions. The...
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2009-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808039834 |
Summary: | In the title compound, [Fe2Sb(C5H5)2(C6H5)3(C7H7NO)2] or [Sb(C6H5)3{Fe(C5H5)(C7H7NO)}2], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oximate ligands in axial positions. The crystal structure is stabilized by two intermolecular C—H...π interactions. |
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ISSN: | 1600-5368 |