Bis(1-ferrocenylethanone oximato)triphenylantimony(V)

Bis(1-ferrocenylethanone oximato)triphenylantimony(V)

In the title compound, [Fe2Sb(C5H5)2(C6H5)3(C7H7NO)2] or [Sb(C6H5)3{Fe(C5H5)(C7H7NO)}2], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oximate ligands in axial positions. The...

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Main Author: Jinshi Fan
Format: Article
Language:English
Published: International Union of Crystallography 2009-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808039834
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spelling doaj-8b287fc5f90745c3ba0d75b6bd9bb0802020-11-25T01:55:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m12m1210.1107/S1600536808039834Bis(1-ferrocenylethanone oximato)triphenylantimony(V)Jinshi FanIn the title compound, [Fe2Sb(C5H5)2(C6H5)3(C7H7NO)2] or [Sb(C6H5)3{Fe(C5H5)(C7H7NO)}2], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oximate ligands in axial positions. The crystal structure is stabilized by two intermolecular C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536808039834
collection DOAJ
language English
format Article
sources DOAJ
author Jinshi Fan
spellingShingle Jinshi Fan
Bis(1-ferrocenylethanone oximato)triphenylantimony(V)
Acta Crystallographica Section E
author_facet Jinshi Fan
author_sort Jinshi Fan
title Bis(1-ferrocenylethanone oximato)triphenylantimony(V)
title_short Bis(1-ferrocenylethanone oximato)triphenylantimony(V)
title_full Bis(1-ferrocenylethanone oximato)triphenylantimony(V)
title_fullStr Bis(1-ferrocenylethanone oximato)triphenylantimony(V)
title_full_unstemmed Bis(1-ferrocenylethanone oximato)triphenylantimony(V)
title_sort bis(1-ferrocenylethanone oximato)triphenylantimony(v)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-01-01
description In the title compound, [Fe2Sb(C5H5)2(C6H5)3(C7H7NO)2] or [Sb(C6H5)3{Fe(C5H5)(C7H7NO)}2], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oximate ligands in axial positions. The crystal structure is stabilized by two intermolecular C—H...π interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808039834
work_keys_str_mv AT jinshifan bis1ferrocenylethanoneoximatotriphenylantimonyv
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