N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)-2-methoxybenzohydrazide

N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)-2-methoxybenzohydrazide

The title compound, C15H12BrClN2O3, was obtained by the condensation reaction between 3-bromo-5-chloro-2-hydroxybenzaldehyde and 2-methoxybenzohydrazide. The molecule is essentially planar, with a dihedral angle between the two benzene rings of 4.7 (2)°, and displays an E...

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Main Author: Jin-Long Hou
Format: Article
Language:English
Published: International Union of Crystallography 2009-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809010198
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spelling doaj-8b2df9be06e14ba1a4c21eb3cac9cbdd2020-11-24T21:31:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654o851o85110.1107/S1600536809010198N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)-2-methoxybenzohydrazideJin-Long HouThe title compound, C15H12BrClN2O3, was obtained by the condensation reaction between 3-bromo-5-chloro-2-hydroxybenzaldehyde and 2-methoxybenzohydrazide. The molecule is essentially planar, with a dihedral angle between the two benzene rings of 4.7 (2)°, and displays an E configuration about the C=N double bond. The molecular conformation is stabilized by intramolecular O—H...N and N—H...O hydrogen bonds. In the crystal structure, molecules are linked into zigzag chains running parallel to the c axis by intermolecular C—H...O hydrogen bonds. The chains are further connected through aromatic π–π stacking interactions with centroid–centroid distances of 3.583 (4) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536809010198
collection DOAJ
language English
format Article
sources DOAJ
author Jin-Long Hou
spellingShingle Jin-Long Hou
N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)-2-methoxybenzohydrazide
Acta Crystallographica Section E
author_facet Jin-Long Hou
author_sort Jin-Long Hou
title N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)-2-methoxybenzohydrazide
title_short N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)-2-methoxybenzohydrazide
title_full N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)-2-methoxybenzohydrazide
title_fullStr N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)-2-methoxybenzohydrazide
title_full_unstemmed N′-(3-Bromo-5-chloro-2-hydroxybenzylidene)-2-methoxybenzohydrazide
title_sort n′-(3-bromo-5-chloro-2-hydroxybenzylidene)-2-methoxybenzohydrazide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-04-01
description The title compound, C15H12BrClN2O3, was obtained by the condensation reaction between 3-bromo-5-chloro-2-hydroxybenzaldehyde and 2-methoxybenzohydrazide. The molecule is essentially planar, with a dihedral angle between the two benzene rings of 4.7 (2)°, and displays an E configuration about the C=N double bond. The molecular conformation is stabilized by intramolecular O—H...N and N—H...O hydrogen bonds. In the crystal structure, molecules are linked into zigzag chains running parallel to the c axis by intermolecular C—H...O hydrogen bonds. The chains are further connected through aromatic π–π stacking interactions with centroid–centroid distances of 3.583 (4) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809010198
work_keys_str_mv AT jinlonghou namp82423bromo5chloro2hydroxybenzylidene2methoxybenzohydrazide
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