Bis[(2-pyridylmethyl)(triisopropylsilyl)amido]zinc(II)–toluene–tetrahydrofuran (4/2/1)
The transamination reaction of (2-pyridylmethyl)(triisopropylsilyl)amine with bis{bis(trimethylsilyl)amido}zinc(II) yields the colorless title solvate, [Zn(C15H27N2Si)2]·0.5C7H8·0.25C4H8O. The title compound was crystallized from toluene and tetrahydrofuran. There are two independe...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680800888X |
| Summary: | The transamination reaction of (2-pyridylmethyl)(triisopropylsilyl)amine with bis{bis(trimethylsilyl)amido}zinc(II) yields the colorless title solvate, [Zn(C15H27N2Si)2]·0.5C7H8·0.25C4H8O. The title compound was crystallized from toluene and tetrahydrofuran. There are two independent molecules in the asymmetric unit. In each molecule, the Zn atom is tetrahedrally coordinated by four N atoms. The two molecules differ in the orientation of the isopropyl groups. The molecules show large N—Zn—N angles [143.0 (2) and 145.7 (2)° between the amide groups]. |
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| ISSN: | 1600-5368 |