catena-Poly[[trimethyltin(IV)]-μ-3,5-difluorobenzoato-κ2O:O′]

In the title compound, [Sn(CH3)3(C7H3F2O2)]n, the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxylate ligands. The five-coordinate Sn atom exists in a distorted trigonal–bip...

Full description

Bibliographic Details
Main Authors: Hong Liu, Handong Yin
Format: Article
Language:English
Published: International Union of Crystallography 2011-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811025608
Description
Summary:In the title compound, [Sn(CH3)3(C7H3F2O2)]n, the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxylate ligands. The five-coordinate Sn atom exists in a distorted trigonal–bipyramidal geometry with the molecules connected by weak C—H...F intermoleclar interactions, forming supramolecular chains parallel to [010].
ISSN:1600-5368