4-Methylanilinium perchlorate 18-crown-6 clathrate

In the title compound, C7H10N+·ClO4−·C12H24O6, the 4-methylanilinium cation interacts with an 18-crown-6 molecule forming a rotator–stator-like structure through bifurcated N—H...(O,O) hydrogen bonds between the ammonium group of th...

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Bibliographic Details
Main Author: Yu-Feng Wang
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811053992
Description
Summary:In the title compound, C7H10N+·ClO4−·C12H24O6, the 4-methylanilinium cation interacts with an 18-crown-6 molecule forming a rotator–stator-like structure through bifurcated N—H...(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether molecule. All three components of the structure possess mirror symmetry. The benzene ring is inclined to the mean plane of the crown ether molecule by 86.84 (8)°.
ISSN:1600-5368