Recognition and Sensing of Chiral Organic Molecules by Chiral Porphyrinoids: A Review

Porphyrinoids are extremely attractive for their electronic, optical, and coordination properties as well as for their versatile substitution at meso/β-positions. All these features allow porphyrinoids to behave as chiroptical hosts for chiral recognition by means of non-covalent interactions toward...

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Bibliographic Details
Main Authors: Gabriele Travagliante, Massimiliano Gaeta, Roberto Purrello, Alessandro D’Urso
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Chemosensors
Subjects:
Online Access:https://www.mdpi.com/2227-9040/9/8/204
Description
Summary:Porphyrinoids are extremely attractive for their electronic, optical, and coordination properties as well as for their versatile substitution at meso/β-positions. All these features allow porphyrinoids to behave as chiroptical hosts for chiral recognition by means of non-covalent interactions towards chiral guests. Over the years, chiral discrimination of chiral molecules such as amino acids, alcohols, amines, hydroxy-carboxylic acids, etc. has aroused the interest of the scientific community. Hence, this review aims to report on the progress to date by illustrating some relevant research regarding the chiral recognition of a multitude of chiral organic guests through several chiral mono- and bis-porphyrins via different spectroscopic techniques.
ISSN:2227-9040