Synthesis of Thioethers by InI3-Catalyzed Substitution of Siloxy Group Using Thiosilanes
The substitution of a siloxy group using thiosilanes smoothly occurred in the presence of InI3 catalyst to yield the corresponding thioethers. InI3 was a specifically effective catalyst in this reaction system, while other typical Lewis acids such as BF3⋅OEt2, AlCl3, and TiCl4 were ineffective. Vari...
Main Authors: | Yoshihiro Nishimoto, Aya Okita, Akio Baba, Makoto Yasuda |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2016-10-01
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Series: | Molecules |
Subjects: | |
Online Access: | http://www.mdpi.com/1420-3049/21/10/1330 |
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