Bis(μ-2,2′-disulfanediyldibenzoato)bis[aqua(2,2′-bipyridine)nickel(II)]

Bis(μ-2,2′-disulfanediyldibenzoato)bis[aqua(2,2′-bipyridine)nickel(II)]

In the centrosymmetric title complex, [Ni2(C14H8O4S2)2(C10H8N2)2(H2O)2], the NiII atom is coordinated by two N atoms from one 2,2′-bipyridine ligand, three carboxylate O atoms (one bidentate and one monodentate) from two different disulfanediyldibenzoate ligands and one O atom from a c...

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Bibliographic Details
Main Authors: Wenlong Liu, Zhengming Liu, Limin Yuan, Jianghua Yu, Botao Qu
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810045824
Description
Summary:In the centrosymmetric title complex, [Ni2(C14H8O4S2)2(C10H8N2)2(H2O)2], the NiII atom is coordinated by two N atoms from one 2,2′-bipyridine ligand, three carboxylate O atoms (one bidentate and one monodentate) from two different disulfanediyldibenzoate ligands and one O atom from a coordinated water molecule in an octahedral coordination geometry. The disulfanediyldibenzoate dianion bridges two NiII atoms. Adjacent molecules are linked through the coordinated water molecules, forming a O—H...O hydrogen-bonded chain running along the a axis.
ISSN:1600-5368

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