[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)

[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)

In the title complex, [CuCl2(C24H24N2O2)], the CuII cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand,...

Full description

Bibliographic Details
Main Authors: Wan-Yun Huang, Dong-Cheng Liu, Han-Chang Wei, Fu-Pei Liang
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811049828
Description
Summary:In the title complex, [CuCl2(C24H24N2O2)], the CuII cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoordinated hydroxy group links with a coordinated chloride anion via an intramolecular O—H...Cl hydrogen bond. Intermolecular N—H...O and N—H...Cl hydrogen bonds occur in the crystal structure.
ISSN:1600-5368

Similar Items