[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)

[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)

In the title complex, [CuCl2(C24H24N2O2)], the CuII cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand,...

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Main Authors: Wan-Yun Huang, Dong-Cheng Liu, Han-Chang Wei, Fu-Pei Liang
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811049828
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spelling doaj-8db13e865bb749de99f1abe72b042e402020-11-24T20:56:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1844m184410.1107/S1600536811049828[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)Wan-Yun HuangDong-Cheng LiuHan-Chang WeiFu-Pei LiangIn the title complex, [CuCl2(C24H24N2O2)], the CuII cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoordinated hydroxy group links with a coordinated chloride anion via an intramolecular O—H...Cl hydrogen bond. Intermolecular N—H...O and N—H...Cl hydrogen bonds occur in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811049828
collection DOAJ
language English
format Article
sources DOAJ
author Wan-Yun Huang
Dong-Cheng Liu
Han-Chang Wei
Fu-Pei Liang
spellingShingle Wan-Yun Huang
Dong-Cheng Liu
Han-Chang Wei
Fu-Pei Liang
[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)
Acta Crystallographica Section E
author_facet Wan-Yun Huang
Dong-Cheng Liu
Han-Chang Wei
Fu-Pei Liang
author_sort Wan-Yun Huang
title [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)
title_short [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)
title_full [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)
title_fullStr [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)
title_full_unstemmed [2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3N,N′,O]dichloridocopper(II)
title_sort [2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol-κ3n,n′,o]dichloridocopper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-12-01
description In the title complex, [CuCl2(C24H24N2O2)], the CuII cation is N,N′,O-chelated by a 2,2′-(1,1′-binaphthyl-2,2′-diyldiimino)diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoordinated hydroxy group links with a coordinated chloride anion via an intramolecular O—H...Cl hydrogen bond. Intermolecular N—H...O and N—H...Cl hydrogen bonds occur in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811049828
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AT dongchengliu 22amp824211amp8242binaphthyl22amp8242diyldiiminodiethanolamp9543nnamp8242odichloridocopperii
AT hanchangwei 22amp824211amp8242binaphthyl22amp8242diyldiiminodiethanolamp9543nnamp8242odichloridocopperii
AT fupeiliang 22amp824211amp8242binaphthyl22amp8242diyldiiminodiethanolamp9543nnamp8242odichloridocopperii
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