One-Pot Hydrothermal Synthesis of Victoria Green (Ca₃Cr₂Si₃O₁₂) Nanoparticles in Alkaline Fluids and Its Colour Hue Characterisation

• Main Authors: J. C. Rendón-Angeles, Z. Matamoros-Veloza, J. L. Rodríguez-Galicia, G. Seong, K. Yanagisawa, A. Tamayo, J. Rubio, L. A. Anaya-Chavira
• Format: Article
• Language: English
• Published: MDPI AG 2021-02-01
• Series: Nanomaterials
• Subjects: Ca₃Cr₂Si₃O₁₂; Victorian green pigment; hydrothermal synthesis; one-pot reaction; hierarchical architecture; nanosized dyes
• Online Access: https://www.mdpi.com/2079-4991/11/2/521

One-pot hydrothermal preparation of Ca₃Cr₂Si₃O₁₂ uvarovite nanoparticles under alkaline conditions was investigated for the first time. The experimental parameters selected for the study considered the concentration of the KOH solvent solution (0.01 to 5.0 M), the agitation of the autoclave (50 rpm), and the nominal content of Si⁴⁺ (2.2–3.0 mole). Fine uvarovite particles were synthesised at 200 °C after a 3 h interval in a highly concentrated 5.0 M KOH solution. The crystallisation of single-phase Ca₃Cr₂Si₃O₁₂ particles proceeded free of by-products via a one-pot process involving a single-step reaction. KOH solutions below 2.5 M and water hindered the crystallisation of the Ca₃Cr₂Si₃O₁₂ particles. The hydrothermal treatments carried out with stirring (50 rpm) and non-stirring triggered the crystallisation of irregular anhedral particles with average sizes of 8.05 and 12.25 nm, respectively. These particles spontaneously assembled into popcorn-shaped agglomerates with sizes varying from 66 to 156 nm. All the powders prepared by the present method exhibited CIE-L*a*b* values that correspond to the Victoria green colour spectral space and have a high near infrared reflectance property. The particle size and structural crystallinity are factors affecting the Victoria pigment optical properties, such as CIE-L*a*b* values, green tonality, and NIR reflectance.