(E)-Benzaldehyde (2,4,6-trichlorophenyl)hydrazone

(E)-Benzaldehyde (2,4,6-trichlorophenyl)hydrazone

The title compound, C13H9Cl3N2, was obtained from a condensation reaction of benzaldehyde and 2,4,6-trichlorophenylhydrazine. The molecule assumes an E configuration with the phenyl ring and trichlorophenyl ring located on opposite sides of the C=N bond. The phenyl ring is oriented at a dihedral ang...

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Main Authors: Yan-Lan Huang, Deng-Feng Li, Jian Sun, Jin-Hua Gao, Shang Shan
Format: Article
Language:English
Published: International Union of Crystallography 2011-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681100328X
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spelling doaj-8e52d9803eb74a07ac6141d0d69ae5b82020-11-25T01:05:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672o528o52810.1107/S160053681100328X(E)-Benzaldehyde (2,4,6-trichlorophenyl)hydrazoneYan-Lan HuangDeng-Feng LiJian SunJin-Hua GaoShang ShanThe title compound, C13H9Cl3N2, was obtained from a condensation reaction of benzaldehyde and 2,4,6-trichlorophenylhydrazine. The molecule assumes an E configuration with the phenyl ring and trichlorophenyl ring located on opposite sides of the C=N bond. The phenyl ring is oriented at a dihedral angle of 42.58 (12)° with respect to the tricholorophenyl ring. In the crystal, the molecules are linked via N—H...N hydrogen bonds, forming supramolecular chains running along the c axis. π–π stacking is present between parallel trichlorophenyl rings of adjacent molecules, the face-to-face and centroid–centroid distances being 3.369 (14) and 3.724 (2) Å, respectively. http://scripts.iucr.org/cgi-bin/paper?S160053681100328X
collection DOAJ
language English
format Article
sources DOAJ
author Yan-Lan Huang
Deng-Feng Li
Jian Sun
Jin-Hua Gao
Shang Shan
spellingShingle Yan-Lan Huang
Deng-Feng Li
Jian Sun
Jin-Hua Gao
Shang Shan
(E)-Benzaldehyde (2,4,6-trichlorophenyl)hydrazone
Acta Crystallographica Section E
author_facet Yan-Lan Huang
Deng-Feng Li
Jian Sun
Jin-Hua Gao
Shang Shan
author_sort Yan-Lan Huang
title (E)-Benzaldehyde (2,4,6-trichlorophenyl)hydrazone
title_short (E)-Benzaldehyde (2,4,6-trichlorophenyl)hydrazone
title_full (E)-Benzaldehyde (2,4,6-trichlorophenyl)hydrazone
title_fullStr (E)-Benzaldehyde (2,4,6-trichlorophenyl)hydrazone
title_full_unstemmed (E)-Benzaldehyde (2,4,6-trichlorophenyl)hydrazone
title_sort (e)-benzaldehyde (2,4,6-trichlorophenyl)hydrazone
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-02-01
description The title compound, C13H9Cl3N2, was obtained from a condensation reaction of benzaldehyde and 2,4,6-trichlorophenylhydrazine. The molecule assumes an E configuration with the phenyl ring and trichlorophenyl ring located on opposite sides of the C=N bond. The phenyl ring is oriented at a dihedral angle of 42.58 (12)° with respect to the tricholorophenyl ring. In the crystal, the molecules are linked via N—H...N hydrogen bonds, forming supramolecular chains running along the c axis. π–π stacking is present between parallel trichlorophenyl rings of adjacent molecules, the face-to-face and centroid–centroid distances being 3.369 (14) and 3.724 (2) Å, respectively.
url http://scripts.iucr.org/cgi-bin/paper?S160053681100328X
work_keys_str_mv AT yanlanhuang ebenzaldehyde246trichlorophenylhydrazone
AT dengfengli ebenzaldehyde246trichlorophenylhydrazone
AT jiansun ebenzaldehyde246trichlorophenylhydrazone
AT jinhuagao ebenzaldehyde246trichlorophenylhydrazone
AT shangshan ebenzaldehyde246trichlorophenylhydrazone
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