Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]
The structure of the title compound, [Li(C5H3N2O2)(H2O)]n, contains an LiI ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxylate ligands with a bridging carboxylate group, and two aqua O atoms also in a bridging mode. T...
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International Union of Crystallography
2012-07-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812024683 |
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doaj-8e615cbc64ea4bf5aa4ede55d8bf13ee2020-11-25T02:24:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m933m93410.1107/S1600536812024683Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]Wojciech StarostaJanusz LeciejewiczThe structure of the title compound, [Li(C5H3N2O2)(H2O)]n, contains an LiI ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxylate ligands with a bridging carboxylate group, and two aqua O atoms also in a bridging mode. The symmetry-related LiI ions bridged by a carboxylate O atom and a coordinating water O atom form an Li2O2 unit with an Li...Li distance of 3.052 (4) Å, which generates molecular ribbons propagating in the c-axis direction. The ribbons are held together by a network of O—H...O hydrogen bonds in which the coordinating water molecules act as donors and the carboxylate O atoms as acceptors.http://scripts.iucr.org/cgi-bin/paper?S1600536812024683 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Wojciech Starosta Janusz Leciejewicz |
spellingShingle |
Wojciech Starosta Janusz Leciejewicz Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium] Acta Crystallographica Section E |
author_facet |
Wojciech Starosta Janusz Leciejewicz |
author_sort |
Wojciech Starosta |
title |
Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium] |
title_short |
Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium] |
title_full |
Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium] |
title_fullStr |
Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium] |
title_full_unstemmed |
Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium] |
title_sort |
poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2012-07-01 |
description |
The structure of the title compound, [Li(C5H3N2O2)(H2O)]n, contains an LiI ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxylate ligands with a bridging carboxylate group, and two aqua O atoms also in a bridging mode. The symmetry-related LiI ions bridged by a carboxylate O atom and a coordinating water O atom form an Li2O2 unit with an Li...Li distance of 3.052 (4) Å, which generates molecular ribbons propagating in the c-axis direction. The ribbons are held together by a network of O—H...O hydrogen bonds in which the coordinating water molecules act as donors and the carboxylate O atoms as acceptors. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812024683 |
work_keys_str_mv |
AT wojciechstarosta polyamp9562aquaamp9562pyrazine2carboxylatolithium AT januszleciejewicz polyamp9562aquaamp9562pyrazine2carboxylatolithium |
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1724855394291941376 |