Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]

Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]

The structure of the title compound, [Li(C5H3N2O2)(H2O)]n, contains an LiI ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxylate ligands with a bridging carboxylate group, and two aqua O atoms also in a bridging mode. T...

Full description

Bibliographic Details
Main Authors: Wojciech Starosta, Janusz Leciejewicz
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812024683
id doaj-8e615cbc64ea4bf5aa4ede55d8bf13ee
record_format Article
spelling doaj-8e615cbc64ea4bf5aa4ede55d8bf13ee2020-11-25T02:24:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m933m93410.1107/S1600536812024683Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]Wojciech StarostaJanusz LeciejewiczThe structure of the title compound, [Li(C5H3N2O2)(H2O)]n, contains an LiI ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxylate ligands with a bridging carboxylate group, and two aqua O atoms also in a bridging mode. The symmetry-related LiI ions bridged by a carboxylate O atom and a coordinating water O atom form an Li2O2 unit with an Li...Li distance of 3.052 (4) Å, which generates molecular ribbons propagating in the c-axis direction. The ribbons are held together by a network of O—H...O hydrogen bonds in which the coordinating water molecules act as donors and the carboxylate O atoms as acceptors.http://scripts.iucr.org/cgi-bin/paper?S1600536812024683
collection DOAJ
language English
format Article
sources DOAJ
author Wojciech Starosta
Janusz Leciejewicz
spellingShingle Wojciech Starosta
Janusz Leciejewicz
Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]
Acta Crystallographica Section E
author_facet Wojciech Starosta
Janusz Leciejewicz
author_sort Wojciech Starosta
title Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]
title_short Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]
title_full Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]
title_fullStr Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]
title_full_unstemmed Poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]
title_sort poly[μ2-aqua-μ2-(pyrazine-2-carboxylato)-lithium]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-07-01
description The structure of the title compound, [Li(C5H3N2O2)(H2O)]n, contains an LiI ion with a distorted trigonal–bipyramidal coordination environment involving the N and O atoms of pyrazine-2-carboxylate ligands with a bridging carboxylate group, and two aqua O atoms also in a bridging mode. The symmetry-related LiI ions bridged by a carboxylate O atom and a coordinating water O atom form an Li2O2 unit with an Li...Li distance of 3.052 (4) Å, which generates molecular ribbons propagating in the c-axis direction. The ribbons are held together by a network of O—H...O hydrogen bonds in which the coordinating water molecules act as donors and the carboxylate O atoms as acceptors.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812024683
work_keys_str_mv AT wojciechstarosta polyamp9562aquaamp9562pyrazine2carboxylatolithium
AT januszleciejewicz polyamp9562aquaamp9562pyrazine2carboxylatolithium
_version_ 1724855394291941376

Similar Items