Bis(1,10-phenanthroline-κ2N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate
In the title compound, [Cu(SO4)(C12H8N2)2]·C3H8O2, the CuII ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N2C2 group...
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International Union of Crystallography
2012-12-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812047721 |
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doaj-8e6a50e1ec9f479b910a4693a8cbd6002020-11-25T00:46:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1555m155510.1107/S1600536812047721Bis(1,10-phenanthroline-κ2N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvateKai-Long ZhongIn the title compound, [Cu(SO4)(C12H8N2)2]·C3H8O2, the CuII ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N2C2 groups subtend a dihedral angle of 71.10 (15)°. In the crystal, the solvent molecule forms two O—H...O hydrogen bonds to its adjacent complex molecule. The chosen crystal was found to be a racemic twin; the presence of pseudosymmetry in the structure suggests the higher symmetry space group C2/c, but attempts to refine the structure in this space group resulted in an unsatisfactory model and high R and wR values.http://scripts.iucr.org/cgi-bin/paper?S1600536812047721 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kai-Long Zhong |
spellingShingle |
Kai-Long Zhong Bis(1,10-phenanthroline-κ2N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate Acta Crystallographica Section E |
author_facet |
Kai-Long Zhong |
author_sort |
Kai-Long Zhong |
title |
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title_short |
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title_full |
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title_fullStr |
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title_full_unstemmed |
Bis(1,10-phenanthroline-κ2N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title_sort |
bis(1,10-phenanthroline-κ2n,n′)(sulfato-o)copper(ii) propane-1,3-diol monosolvate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2012-12-01 |
description |
In the title compound, [Cu(SO4)(C12H8N2)2]·C3H8O2, the CuII ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N2C2 groups subtend a dihedral angle of 71.10 (15)°. In the crystal, the solvent molecule forms two O—H...O hydrogen bonds to its adjacent complex molecule. The chosen crystal was found to be a racemic twin; the presence of pseudosymmetry in the structure suggests the higher symmetry space group C2/c, but attempts to refine the structure in this space group resulted in an unsatisfactory model and high R and wR values. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812047721 |
work_keys_str_mv |
AT kailongzhong bis110phenanthrolineamp9542nnamp8242sulfatoocopperiipropane13diolmonosolvate |
_version_ |
1725265010988417024 |