Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate

Benzyl 3-[(E)-(furan-2-yl)methylidene]-2-methyldithiocarbazate

In the title compound, C14H14N2OS2, the furan ring exhibits rotational disorder over two orientations, with an occupancy ratio of 0.508 (7):0.492 (7). The furan and phenyl rings form dihedral angles of 8.2 (6) (major occupancy component), 14.8 ...

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Bibliographic Details
Main Authors: Benu K. Dey, Sebastian Suarez, Biplab Ganguly, Fabio Doctorovich, Tapashi G. Roy
Format: Article
Language:English
Published: International Union of Crystallography 2012-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812035520
Description
Summary:In the title compound, C14H14N2OS2, the furan ring exhibits rotational disorder over two orientations, with an occupancy ratio of 0.508 (7):0.492 (7). The furan and phenyl rings form dihedral angles of 8.2 (6) (major occupancy component), 14.8 (6) (minor occupancy component) and 73.65 (9)°, respectively, with the central residue (C4N2S2), indicating a twisted conformation for the molecule. The methyl group and the thione S atom are syn and the conformation about the imine bond is E. In the crystal, C—H...π interactions involving the phenyl ring are observed.
ISSN:1600-5368

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