Enhanced Magnetoelectric Coupling in BaTiO<sub>3</sub>-BiFeO<sub>3</sub> Multilayers—An Interface Effect
Combining various (multi-)ferroic materials into heterostructures is a promising route to enhance their inherent properties, such as the magnetoelectric coupling in BiFeO<sub>3</sub> thin films. We have previously reported on the up-to-tenfold increase of the magnetoelectric voltage coef...
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doaj-8ee6dbd7555e4f32a66659e5464bbdcb2020-11-25T01:12:56ZengMDPI AGMaterials1996-19442020-01-0113119710.3390/ma13010197ma13010197Enhanced Magnetoelectric Coupling in BaTiO<sub>3</sub>-BiFeO<sub>3</sub> Multilayers—An Interface EffectStefan Hohenberger0Johanna K. Jochum1Margriet J. Van Bael2Kristiaan Temst3Christian Patzig4Thomas Höche5Marius Grundmann6Michael Lorenz7Felix-Bloch-Institut für Festkörperphysik, Universität Leipzig, Linnéstraße 5, D-04103 Leipzig, GermanyQuantum Solid State Physics, Celestijnenlaan 200D, B-3001 Leuven, BelgiumQuantum Solid State Physics, Celestijnenlaan 200D, B-3001 Leuven, BelgiumQuantum Solid State Physics, Celestijnenlaan 200D, B-3001 Leuven, BelgiumCenter for Applied Microstructure Diagnostics, Fraunhofer-Institut für Mikrostruktur von Werkstoffen und Systemen, Walter-Hülse-Straße 1, D-06120 Halle, GermanyCenter for Applied Microstructure Diagnostics, Fraunhofer-Institut für Mikrostruktur von Werkstoffen und Systemen, Walter-Hülse-Straße 1, D-06120 Halle, GermanyFelix-Bloch-Institut für Festkörperphysik, Universität Leipzig, Linnéstraße 5, D-04103 Leipzig, GermanyFelix-Bloch-Institut für Festkörperphysik, Universität Leipzig, Linnéstraße 5, D-04103 Leipzig, GermanyCombining various (multi-)ferroic materials into heterostructures is a promising route to enhance their inherent properties, such as the magnetoelectric coupling in BiFeO<sub>3</sub> thin films. We have previously reported on the up-to-tenfold increase of the magnetoelectric voltage coefficient <inline-formula> <math display="inline"> <semantics> <msub> <mi>α</mi> <mi>ME</mi> </msub> </semantics> </math> </inline-formula> in BaTiO<sub>3</sub>-BiFeO<sub>3</sub> multilayers relative to BiFeO<sub>3</sub> single layers. Unraveling the origin and mechanism of this enhanced effect is a prerequisite to designing new materials for the application of magnetoelectric devices. By careful variations in the multilayer design we now present an evaluation of the influences of the BaTiO<sub>3</sub>-BiFeO<sub>3</sub> thickness ratio, oxygen pressure during deposition, and double layer thickness. Our findings suggest an interface driven effect at the core of the magnetoelectric coupling effect in our multilayers superimposed on the inherent magnetoelectric coupling of BiFeO<sub>3</sub> thin films, which leads to a giant <inline-formula> <math display="inline"> <semantics> <msub> <mi>α</mi> <mi>ME</mi> </msub> </semantics> </math> </inline-formula> coefficient of 480 <inline-formula> <math display="inline"> <semantics> <mi mathvariant="normal">V</mi></semantics></math></inline-formula><inline-formula><math display="inline"><semantics><mi mathvariant="normal">c</mi></semantics></math></inline-formula><inline-formula><math display="inline"> <semantics> <mi mathvariant="normal">m</mi> </semantics></math></inline-formula><inline-formula><math display="inline"><semantics><msup><mrow></mrow> <mrow> <mo>−</mo> <mn>1</mn> </mrow> </msup> </semantics> </math> </inline-formula> Oe<inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mrow> <mo>−</mo> <mn>1</mn> </mrow> </msup> </semantics> </math> </inline-formula> for a <inline-formula> <math display="inline"> <semantics> <mrow> <mn>16</mn> <mo>×</mo> </mrow> </semantics> </math> </inline-formula>(BaTiO<sub>3</sub>-BiFeO<sub>3</sub>) superlattice with a <inline-formula> <math display="inline"> <semantics> <mrow> <mn>4.8</mn> </mrow> </semantics> </math> </inline-formula> nm double layer periodicity.https://www.mdpi.com/1996-1944/13/1/197multiferroicmagnetoelectricoxide superlattices |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Stefan Hohenberger Johanna K. Jochum Margriet J. Van Bael Kristiaan Temst Christian Patzig Thomas Höche Marius Grundmann Michael Lorenz |
spellingShingle |
Stefan Hohenberger Johanna K. Jochum Margriet J. Van Bael Kristiaan Temst Christian Patzig Thomas Höche Marius Grundmann Michael Lorenz Enhanced Magnetoelectric Coupling in BaTiO<sub>3</sub>-BiFeO<sub>3</sub> Multilayers—An Interface Effect Materials multiferroic magnetoelectric oxide superlattices |
author_facet |
Stefan Hohenberger Johanna K. Jochum Margriet J. Van Bael Kristiaan Temst Christian Patzig Thomas Höche Marius Grundmann Michael Lorenz |
author_sort |
Stefan Hohenberger |
title |
Enhanced Magnetoelectric Coupling in BaTiO<sub>3</sub>-BiFeO<sub>3</sub> Multilayers—An Interface Effect |
title_short |
Enhanced Magnetoelectric Coupling in BaTiO<sub>3</sub>-BiFeO<sub>3</sub> Multilayers—An Interface Effect |
title_full |
Enhanced Magnetoelectric Coupling in BaTiO<sub>3</sub>-BiFeO<sub>3</sub> Multilayers—An Interface Effect |
title_fullStr |
Enhanced Magnetoelectric Coupling in BaTiO<sub>3</sub>-BiFeO<sub>3</sub> Multilayers—An Interface Effect |
title_full_unstemmed |
Enhanced Magnetoelectric Coupling in BaTiO<sub>3</sub>-BiFeO<sub>3</sub> Multilayers—An Interface Effect |
title_sort |
enhanced magnetoelectric coupling in batio<sub>3</sub>-bifeo<sub>3</sub> multilayers—an interface effect |
publisher |
MDPI AG |
series |
Materials |
issn |
1996-1944 |
publishDate |
2020-01-01 |
description |
Combining various (multi-)ferroic materials into heterostructures is a promising route to enhance their inherent properties, such as the magnetoelectric coupling in BiFeO<sub>3</sub> thin films. We have previously reported on the up-to-tenfold increase of the magnetoelectric voltage coefficient <inline-formula> <math display="inline"> <semantics> <msub> <mi>α</mi> <mi>ME</mi> </msub> </semantics> </math> </inline-formula> in BaTiO<sub>3</sub>-BiFeO<sub>3</sub> multilayers relative to BiFeO<sub>3</sub> single layers. Unraveling the origin and mechanism of this enhanced effect is a prerequisite to designing new materials for the application of magnetoelectric devices. By careful variations in the multilayer design we now present an evaluation of the influences of the BaTiO<sub>3</sub>-BiFeO<sub>3</sub> thickness ratio, oxygen pressure during deposition, and double layer thickness. Our findings suggest an interface driven effect at the core of the magnetoelectric coupling effect in our multilayers superimposed on the inherent magnetoelectric coupling of BiFeO<sub>3</sub> thin films, which leads to a giant <inline-formula> <math display="inline"> <semantics> <msub> <mi>α</mi> <mi>ME</mi> </msub> </semantics> </math> </inline-formula> coefficient of 480 <inline-formula> <math display="inline"> <semantics> <mi mathvariant="normal">V</mi></semantics></math></inline-formula><inline-formula><math display="inline"><semantics><mi mathvariant="normal">c</mi></semantics></math></inline-formula><inline-formula><math display="inline"> <semantics> <mi mathvariant="normal">m</mi> </semantics></math></inline-formula><inline-formula><math display="inline"><semantics><msup><mrow></mrow> <mrow> <mo>−</mo> <mn>1</mn> </mrow> </msup> </semantics> </math> </inline-formula> Oe<inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mrow> <mo>−</mo> <mn>1</mn> </mrow> </msup> </semantics> </math> </inline-formula> for a <inline-formula> <math display="inline"> <semantics> <mrow> <mn>16</mn> <mo>×</mo> </mrow> </semantics> </math> </inline-formula>(BaTiO<sub>3</sub>-BiFeO<sub>3</sub>) superlattice with a <inline-formula> <math display="inline"> <semantics> <mrow> <mn>4.8</mn> </mrow> </semantics> </math> </inline-formula> nm double layer periodicity. |
topic |
multiferroic magnetoelectric oxide superlattices |
url |
https://www.mdpi.com/1996-1944/13/1/197 |
work_keys_str_mv |
AT stefanhohenberger enhancedmagnetoelectriccouplinginbatiosub3subbifeosub3submultilayersaninterfaceeffect AT johannakjochum enhancedmagnetoelectriccouplinginbatiosub3subbifeosub3submultilayersaninterfaceeffect AT margrietjvanbael enhancedmagnetoelectriccouplinginbatiosub3subbifeosub3submultilayersaninterfaceeffect AT kristiaantemst enhancedmagnetoelectriccouplinginbatiosub3subbifeosub3submultilayersaninterfaceeffect AT christianpatzig enhancedmagnetoelectriccouplinginbatiosub3subbifeosub3submultilayersaninterfaceeffect AT thomashoche enhancedmagnetoelectriccouplinginbatiosub3subbifeosub3submultilayersaninterfaceeffect AT mariusgrundmann enhancedmagnetoelectriccouplinginbatiosub3subbifeosub3submultilayersaninterfaceeffect AT michaellorenz enhancedmagnetoelectriccouplinginbatiosub3subbifeosub3submultilayersaninterfaceeffect |
_version_ |
1725164309122646016 |